Diazene, bis(3-bromophenyl)-, (Z)-

Base Information

• Chemical Name: Diazene, bis(3-bromophenyl)-, (Z)-
• CAS No.: 63213-03-6
• Molecular Formula: C₁₂H₈Br₂N₂
• Molecular Weight: 340.017
• Mol file: 63213-03-6.mol

Synonyms:

Chemical Property of Diazene, bis(3-bromophenyl)-, (Z)-

Chemical Property:

• PSA: 24.72000
• LogP: 5.62700

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Diazene, bis(3-bromophenyl)-, (Z)-

There total 17 articles about Diazene, bis(3-bromophenyl)-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

m-nitrobromobenzene (585-79-5) → 1,2-bis(3-bromophenyl)diazene (63213-03-6,15426-17-2)

Guidance literature:

With sodium tetrahydroborate; bismuthene; In ethanol; at 25 ℃; for 24h; chemoselective reaction;

DOI:10.1039/c5ra17994g

Reference yield: 93.0%

bis-(3-bromo-phenyl)-diazene-N-oxide (23377-24-4) → 1,2-bis(3-bromophenyl)diazene (63213-03-6,15426-17-2)

Guidance literature:

With sodium hydroxide; Bakers'yeast; In ethanol; water; for 12h; Heating;

DOI:10.1016/S0040-4039(96)02464-1

Reference yield: 91.0%

m-Bromoaniline (591-19-5) → 1,2-bis(3-bromophenyl)diazene (63213-03-6,15426-17-2)

Guidance literature:

With [bis(acetoxy)iodo]benzene; In dichloromethane; at 20 - 25 ℃; for 0.5h;

DOI:10.1016/j.tet.2012.07.012

upstream raw materials:

ethanol

m-nitrobromobenzene

1,2-bis(3-bromophenyl)diazene oxide

1,2-bis(3-bromophenyl)hydrazine

Downstream raw materials:

5-bromo-2-fluoroaniline

Refernces

• 1、 Abadi, Ashraf H.,Abdel-Halim, Mohammad,El-Sharkawy, Lina Y.,Engel, Matthias,Fathalla, Reem K.,Mokbel, Salma A.. "Synthesis of novel 1,2-diarylpyrazolidin-3-one–based compounds and their evaluation as broad spectrum antibacterial agents". . . Retrieved 2020/03/30.
• 2、 Chen, Gong-Jun,Xin, Wen-Ling,Wang, Jing-Si,Cheng, Jun-Yan,Dong, Yu-Bin. "Visible-light triggered selective reduction of nitroarenes to azo compounds catalysed by Ag@organic molecular cages". supporting information. p. 3586 - 3589. Retrieved 2019/03/26.