beta-D-Mannopyranose

Base Information

• Chemical Name: beta-D-Mannopyranose
• CAS No.: 7322-31-8
• Molecular Formula: C6H12O6
• Molecular Weight: 180.158
• UNII: CUO87O37MT
• DSSTox Substance ID: DTXSID501015877
• Nikkaji Number: J15.394J
• Wikidata: Q27103775
• Metabolomics Workbench ID: 51767
• Mol file: 7322-31-8.mol

Synonyms:Hb Randwick;hemoglobin Randwick

Chemical Property of beta-D-Mannopyranose

Chemical Property:

• Boiling Point: 410.8°Cat760mmHg
• Flash Point: 202.2°C
• PSA: 110.38000
• Density: 1.732g/cm³
• LogP: -3.22140
• XLogP3: -2.6
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 180.06338810
• Heavy Atom Count: 12
• Complexity: 151

Purity/Quality:

98%, ^*data from raw suppliers

(2R,3S,4S,5S,6R)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C1C(C(C(C(O1)O)O)O)O)O
• Isomeric SMILES: C([C@@H]1[C@H]([C@@H]([C@@H]([C@@H](O1)O)O)O)O)O

Technology Process of beta-D-Mannopyranose

There total 5 articles about beta-D-Mannopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C24H42O21 → β-D-glucose (492-61-5) + alpha-D-glucopyranose (492-62-6) + β-D-mannose (7322-31-8)

Guidance literature:

With sulfuric acid; at 120 ℃; for 1h; Overall yield = 238 mg;

DOI:10.1016/j.carres.2013.02.012

Reference yield:

4-O-β-D-mannopyranosyl-D-glucopyranose (29276-55-9) → β-D-glucose (492-61-5) + alpha-D-glucopyranose (492-62-6) + β-D-mannose (7322-31-8)

Guidance literature:

With sulfuric acid; at 120 ℃; for 1h; Overall yield = 180 mg;

DOI:10.1016/j.carres.2013.02.012

Reference yield:

O-β-D-Mannopyranosyl(1->4)-O-β-D-mannopyranosyl(1->4)-D-glucopyranose (6401-81-6,17659-52-8,19141-16-3,20702-55-0,52485-13-9,69429-19-2,80446-86-2,80446-87-3,94799-30-1,94799-74-3,113158-51-3,118396-93-3,121153-20-6,133267-59-1,142185-35-1) → β-D-glucose (492-61-5) + alpha-D-glucopyranose (492-62-6) + β-D-mannose (7322-31-8)

Guidance literature:

With sulfuric acid; at 120 ℃; for 1h; Overall yield = 174 mg;

DOI:10.1016/j.carres.2013.02.012

upstream raw materials:

formaldehyd

4-O-β-D-mannopyranosyl-D-glucopyranose

O-β-D-Mannopyranosyl(1->4)-O-β-D-mannopyranosyl(1->4)-D-glucopyranose

Downstream raw materials:

2-oxopropanal

1,6-anhydro-2,3-O-isopropylidene-β-D-mannopyranose

mannosan

β-D-glucose

Refernces

• 1、 Lins, Roger J.,Flitsch, Sabine L.,Turner, Nicholas J.,Irving, Ed,Brown, Stuart A.. "Enzymatic generation and in situ screening of a dynamic combinatorial library of sialic acid analogues". . p. 3405 - 3407. Retrieved 2007/10/03.