12-Tridecenal

Base Information

• Chemical Name: 12-Tridecenal
• CAS No.: 63618-39-3
• Molecular Formula: C13H24O
• Molecular Weight: 196.333
• Mol file: 63618-39-3.mol

Synonyms:12-Tridecenal;

Chemical Property of 12-Tridecenal

Chemical Property:

• Melting Point: 5°C (estimate)
• Refractive Index: 1.4543 (estimate)
• Boiling Point: 283.24°C (estimate)
• PSA: 17.07000
• Density: 0.8574 (estimate)
• LogP: 4.27230

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 12-Tridecenal

There total 1 articles about 12-Tridecenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclotridecanone (832-10-0) → tridec-12-en-2-one (60437-21-0) + tridec-12-enal (63618-39-3) + trans-Bicyclo<9.2.0>tridecan-1-ol (35522-57-7,35522-58-8,58946-26-2) + cis-Bicyclo<9.2.0>tridecan-1-ol (35522-57-7,35522-58-8,58946-26-2)

Guidance literature:

With zeolite LiY; for 2h; Product distribution; Mechanism; Irradiation; other alkali zeolites; also irradiation in isotropic solvents;

DOI:10.1016/0040-4039(91)80562-K

Reference yield:

tridec-12-enal (63618-39-3) → 12-tridecenoic acid (6006-06-0)

Guidance literature:

With sodium chlorite; Yield given;

DOI:10.1016/S0040-4039(97)00285-2

Reference yield:

tridec-12-enal (63618-39-3) → (E)-12,13-dihydroxytridec-2-en-1-yl benzoate

Guidance literature:

Multi-step reaction with 4 steps

1: sodium hydride / tetrahydrofuran / Inert atmosphere

2: diisobutylaluminium hydride / 1 h / 0 °C / Inert atmosphere

3: dmap; triethylamine / dichloromethane / 14 h / 23 °C / Inert atmosphere

4: ruthenium trichloride; sodium periodate / Inert atmosphere

With dmap; ruthenium trichloride; sodium periodate; sodium hydride; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; dichloromethane;

DOI:10.1021/acs.orglett.9b01204

upstream raw materials:

cyclotridecanone

Downstream raw materials:

12-tridecenoic acid

C₂₀H₃₂O₂

Refernces