1-Naphthalenesulfonic acid, 6-diazo-5,6-dihydro-5-oxo-, 4-benzoyl-1,3-phenylene ester

Base Information

• Chemical Name: 1-Naphthalenesulfonic acid, 6-diazo-5,6-dihydro-5-oxo-, 4-benzoyl-1,3-phenylene ester
• CAS No.: 31001-73-7
• Deprecated CAS: 111373-09-2
• Molecular Formula: C₃₃H₁₈N₄O₉S₂
• Molecular Weight: 678.659
• European Community (EC) Number: 250-425-2
• NSC Number: 343232
• UNII: F6HME325R3
• DSSTox Substance ID: DTXSID7067586
• Nikkaji Number: J287.424E
• Mol file: 31001-73-7.mol

Synonyms:31001-73-7;1-Naphthalenesulfonic acid, 6-diazo-5,6-dihydro-5-oxo-, 4-benzoyl-1,3-phenylene ester;NSC 343232;4-Benzoyl-1,3-phenylene bis(6-diazo-5,6-dihydro-5-oxonaphthalene-1-sulphonate);F6HME325R3;EINECS 250-425-2;4-BENZOYL-1,3-PHENYLENE BIS(6-DIAZO-5,6-DIHYDRO-5-OXONAPHTHALENE-1-SULFONATE);NSC-343232;5-[4-benzoyl-3-(6-diazonio-5-oxidonaphthalen-1-yl)sulfonyloxyphenoxy]sulfonyl-2-diazonionaphthalen-1-olate;1-Naphthalenesulfonic acid, 6-diazo-5,6-dihydro-5-oxo-, 1,1'-(4-benzoyl-1,3-phenylene) ester;1-Naphthalenesulfonicacid, 6-diazo-5,6-dihydro-5-oxo-, 1,1'-(4-benzoyl-1,3-phenylene) ester;2,4-Dihydroxybenzophenone, 2-diazo-1,2-dihydro-1-oxo-5-naphthalenesulfonate diester;UNII-F6HME325R3;DTXSID7067586;C33H18N4O9S2;NSC343232;C33-H18-N4-O9-S2;2, 2-diazo-1,2-dihydro-1-oxo-5-naphthalenesulfonate diester;1-Naphthalenesulfonic acid,6-dihydro-5-oxo-, 4-benzoyl-1,3-phenylene ester;2,4-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy) benzophenone;2,4-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy)benzophenone;1-Naphthalenesulfonic acid,6-dihydro-5-oxo-, diester with 2,4-dihydroxybenzophenone;Bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonic acid)4-benzoyl-1,3-phenylene ester

Chemical Property of 1-Naphthalenesulfonic acid, 6-diazo-5,6-dihydro-5-oxo-, 4-benzoyl-1,3-phenylene ester

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 229.49000
• Density: g/cm³
• LogP: 6.53732
• XLogP3: 9.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 8
• Exact Mass: 678.05152051
• Heavy Atom Count: 48
• Complexity: 1490

Purity/Quality:

99%, ^*data from raw suppliers

4-Benzoyl-1,3-phenylenebis(6-diazo-5,6-dihydro-5-oxonaphthalene-1-sulphonate) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=O)C2=C(C=C(C=C2)OS(=O)(=O)C3=CC=CC4=C3C=CC(=C4[O-])[N+]#N)OS(=O)(=O)C5=CC=CC6=C5C=CC(=C6[O-])[N+]#N

Technology Process of 1-Naphthalenesulfonic acid, 6-diazo-5,6-dihydro-5-oxo-, 4-benzoyl-1,3-phenylene ester

There total 2 articles about 1-Naphthalenesulfonic acid, 6-diazo-5,6-dihydro-5-oxo-, 4-benzoyl-1,3-phenylene ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2.4-dihydroxybenzophenone (131-56-6) + 2-diazo-1-oxo-1,2-dihydronaphthalene-4-sulfonyl chloride (1001756-09-7,3770-97-6) → 2,4-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy)benzophenone (31001-73-7)

Guidance literature:

With potassium hydroxide; 18-crown-6 ether;

DOI:10.1002/oms.1210230604

Reference yield:

→ 2,4-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy)benzophenone (31001-73-7)

Guidance literature:

entspr. Diol, entspr. Sulfochlorid;

Reference yield:

2,4-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy)benzophenone (31001-73-7) → C33H18O9S2

Guidance literature:

In acetonitrile; at 16.84 ℃; Temperature; Solvent; Wavelength; Quantum yield; Irradiation;

DOI:10.3998/ark.5550190.0012.915

upstream raw materials:

2.4-dihydroxybenzophenone

2-diazo-1-oxo-1,2-dihydronaphthalene-4-sulfonyl chloride

Refernces

• 1、 Kyranos, James N.,du Sorbier, Bertrand M.,Wronka, John,Vouros, Paul,Kirby, Daniel P.. "Reduction Processes in the Fast Atom Bombardment Mass Spectrometry of Sulfonyl Esters of Diazonaphthalenones". . p. 443 - 452. Retrieved 2007/10/02.
• 2、 -. "Method of purifying 2,4-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy benzophenone)". . . Retrieved 2008/06/13.