TRIMETHYLHYDRAZINE

Base Information

• Chemical Name: TRIMETHYLHYDRAZINE
• CAS No.: 1741-01-1
• Molecular Formula: C3H10N2
• Molecular Weight: 74.1258
• Hs Code.: 2928000090
• Mol file: 1741-01-1.mol

Synonyms:1,1,2-Trimethylhydrazine;N,N,N'-Trimethylhydrazine;Trimethylhydrazine;

Chemical Property of TRIMETHYLHYDRAZINE

Chemical Property:

• Vapor Pressure: 300mmHg at 25°C
• Melting Point: -71.91°C
• Refractive Index: 1.408
• Boiling Point: 49.3 °C at 760 mmHg
• PKA: 9.15±0.70(Predicted)
• PSA: 15.27000
• Density: 0.787 g/cm³
• LogP: 0.07330

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethylhydrazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIMETHYLHYDRAZINE

There total 7 articles about TRIMETHYLHYDRAZINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

formic acid N',N'-dimethylhydrazide (3298-49-5) → Trimethylhydrazin (1741-01-1)

Guidance literature:

With lithium aluminium tetrahydride; In 1,4-dioxane; at 50 ℃; for 3.16667h; Solvent; Temperature; Inert atmosphere; Large scale;

DOI:10.1021/op0342022

Reference yield:

N-methyl-N-(methyleneamino)methanamine (2035-89-4) → Trimethylhydrazin (1741-01-1)

Guidance literature:

With lithium aluminium tetrahydride; diethyl ether;

DOI:10.1021/ja01108a044

Reference yield:

<α-N-Methyl-β,β-N,N-dimethylhydrazin>-triphenylphosphonium-iodid → Trimethylhydrazin (1741-01-1)

Guidance literature:

With potassium hydroxide; In ethanol;

DOI:10.1021/jo01029a074

upstream raw materials:

diethyl ether

1,2-Dimethylhydrazine

methylmagnesium bromide

N-methyl-N-(methyleneamino)methanamine

Downstream raw materials:

formyltrimethylhydrazine

4-(trimethylhydrazino-methoxy)-morpholine

1,2,2-Trimethyl-hydrazin-2-carbonsaeureethylester

N'-cyclohexylidene-N,N-dimethyl-hydrazine

Refernces

• 1、 Nigst, Tobias A.,Ammer, Johannes,Mayr, Herbert. "Ambident reactivities of methylhydrazines". supporting information; body text. p. 1353 - 1356. Retrieved 2012/03/27.