Tris(2-chlorophenyl) phosphate

Base Information

• Chemical Name: Tris(2-chlorophenyl) phosphate
• CAS No.: 631-44-7
• Molecular Formula: C18H12Cl3O4P
• Molecular Weight: 429.62
• Mol file: 631-44-7.mol

Synonyms:2-chlorophenyl phosphate;

Chemical Property of Tris(2-chlorophenyl) phosphate

Chemical Property:

• Vapor Pressure: 2.18E-08mmHg at 25°C
• Boiling Point: 465.2°C at 760 mmHg
• Flash Point: 387.8°C
• PSA: 54.57000
• Density: 1.462g/cm³
• LogP: 7.29170

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tris(2-chlorophenyl) phosphate

There total 2 articles about Tris(2-chlorophenyl) phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

sodium 2-chlorophenoxide (35535-81-0) → phosphoric acid tris-(2-chloro-phenyl ester) (631-44-7)

Guidance literature:

With Amberlyst A-26 chloride; trichlorophosphate; In benzene; for 1.08333h; Ambient temperature;

DOI:10.1080/00397919408010211

Reference yield: 89.0%

2-monochlorophenol (95-57-8) → phosphoric acid tris-(2-chloro-phenyl ester) (631-44-7)

Guidance literature:

With sodium hydroxide; trichlorophosphate; for 2.5h; Microwave irradiation;

DOI:10.1080/00304940009355923

upstream raw materials:

2-monochlorophenol

sodium 2-chlorophenoxide

Refernces

• 1、 Kore, A. R.,Sagar, A. D.,Salunkhe, M. M.. "EFFICIENT METHOD FOR THE SYNTHESIS OF TRIARYL PHOSPHATES BY USING PTC AND DIBENZO--CROWN-6". . p. 85 - 86. Retrieved 2007/10/02.
• 2、 Heinicke, J.,Kadyrov, R.,Kellner, K.,Nietzschmann, E.,Tzschach, A.. "1,3-CARBANIONISCHE UMLAGERUNGEN SYNTHESE VON BIS(o-HYDROXYARYL)-PHOSPHORVERBINDUNGEN". . p. 209 - 216. Retrieved 2007/10/02.