DIBENZYLCYANAMIDE

Base Information

• Chemical Name: DIBENZYLCYANAMIDE
• CAS No.: 2451-91-4
• Molecular Formula: C15H14 N2
• Molecular Weight: 222.29
• Hs Code.: 2926909090
• Mol file: 2451-91-4.mol

Synonyms:Cyanamide,bis(phenylmethyl)- (9CI); Cyanamide, dibenzyl- (6CI,7CI,8CI);Dibenzylcyanamide; N,N-Dibenzylcyanamide; NSC 7184

Chemical Property of DIBENZYLCYANAMIDE

Chemical Property:

• Vapor Pressure: 1.03E-07mmHg at 25°C
• Melting Point: 54 °C
• Boiling Point: 148 °C / 10mmHg
• Flash Point: 192.1°C
• PSA: 27.03000
• Density: 1.11g/cm³
• LogP: 3.16988
• Solubility.: soluble in Methanol

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dibenzylcyanamide >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIBENZYLCYANAMIDE

There total 26 articles about DIBENZYLCYANAMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

bromocyane (506-68-3) + dibenzylamine (103-49-1) → N,N-dibenzylcyanamide (2451-91-4)

Guidance literature:

With sodium hydrogencarbonate; In dichloromethane; water; at 0 - 20 ℃; for 16.5h;

DOI:10.1016/j.tetlet.2014.06.019

Reference yield: 87.0%

N-bis(phenylmethyl)-urea (3282-27-7) → N,N-dibenzylcyanamide (2451-91-4)

Guidance literature:

With dichlorocarbene; 18-crown-6 ether; In potassium hydroxide; chloroform; at 30 - 40 ℃;

Reference yield: 83.0%

N-cyanoimidazole (36289-36-8) + dibenzylamine (103-49-1) → N,N-dibenzylcyanamide (2451-91-4)

Guidance literature:

In dichloromethane; at 20 ℃; for 3h;

DOI:10.1021/ol0055263

upstream raw materials:

bromocyane

tribenzylamine

3-(dibenzylamino)prop-1-ene

N,N,N′,N′-tetrabenzylmethanediamine

Downstream raw materials:

dibenzylamine

N²,N²-dibenzyl-[1,3,5]triazine-2,4,6-triyltriamine

Refernces

• 1、 Melekhova, Anna A.,Novikov, Alexander S.,Dubovtsev, Alexey Yu.,Zolotarev, Andrey A.,Bokach, Nadezhda A.. "Tris(3,5-dimethylpyrazolyl)methane copper(I) complexes featuring one disubstituted cyanamide ligand". . p. 69 - 74. Retrieved 2018/09/22.
• 2、 Liang, Honggang,Bao, Lingxiang,Du, Yao,Zhang, Yiying,Pang, Siping,Sun, Chenghui. "Synthesis of Cyanamides from Cyanogen Bromide under Mild Conditions through N-Cyanation of Allylic Tertiary Amines". supporting information. p. 2675 - 2679. Retrieved 2017/10/06.