2-(3-Cyclohexenyl)ethyltrimethoxysilane

Base Information

• Chemical Name: 2-(3-Cyclohexenyl)ethyltrimethoxysilane
• CAS No.: 67592-36-3
• Molecular Formula: C11H22O3Si
• Molecular Weight: 230.379
• European Community (EC) Number: 266-749-2
• DSSTox Substance ID: DTXSID30886839
• Nikkaji Number: J333.209H
• Mol file: 67592-36-3.mol

Synonyms:67592-36-3;2-(3-Cyclohexenyl)ethyltrimethoxysilane;(2-(cyclohex-3-en-1-yl)ethyl)trimethoxysilane;2-cyclohex-3-en-1-ylethyl(trimethoxy)silane;Silane, [2-(3-cyclohexen-1-yl)ethyl]trimethoxy-;[2-(3-cyclohexenyl)ethyl]trimethoxysilane;Silane, (2-(3-cyclohexen-1-yl)ethyl)trimethoxy-;EINECS 266-749-2;(2-(3-Cyclohexenyl)ethyl)trimethoxysilane;[2-(3-cyclohexen-1-yl)ethyl]trimethoxysilane;(2-(3-Cyclohexen-1-yl)ethyl)trimethoxysilane;[2-(cyclohex-3-en-1-yl)ethyl]trimethoxysilane;SCHEMBL137566;C11-H22-O3-Si;DTXSID30886839;MFCD00054755;(2-(cyclohex-3-enyl)ethyl)trimethoxysilane;[2-(3-Cyclohexenyl)ethyl]trimethoxy-silane;Cyclohexene, 4-(2-(trimethoxysilyl)ethyl)-

Chemical Property of 2-(3-Cyclohexenyl)ethyltrimethoxysilane

Chemical Property:

• Vapor Pressure: 0.0601mmHg at 25°C
• Melting Point: <0 ºC
• Refractive Index: 1.446
• Boiling Point: 240 °C at 760 mmHg
• Flash Point: 98.1 °C
• PSA: 27.69000
• Density: 0.953 g/cm³
• LogP: 2.61090
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 230.13382109
• Heavy Atom Count: 15
• Complexity: 194

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-(3-CYCLOHEXENYL)ETHYLTRIMETHOXYSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CO[Si](CCC1CCC=CC1)(OC)OC

Technology Process of 2-(3-Cyclohexenyl)ethyltrimethoxysilane

There total 3 articles about 2-(3-Cyclohexenyl)ethyltrimethoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

trimethoxysilane (2487-90-3) + 4-ethenylcyclohexene (100-40-3) → (2-(cyclohex-3-en-1-yl)ethyl)trimethoxysilane (67592-36-3)

Guidance literature:

With 2C₄H₉O^(1-)*Ni⁽²⁺⁾*(x)KCl; In tetrahydrofuran; at 20 ℃; for 12h; Glovebox; Inert atmosphere;

DOI:10.1002/anie.201606832

Reference yield:

4-ethenylcyclohexene (100-40-3) → (2-(cyclohex-3-en-1-yl)ethyl)trimethoxysilane (67592-36-3)

Guidance literature:

Multi-step reaction with 2 steps

1: HSiCl₃, H₂PtCl₆*6H₂O / benzene; tetrahydrofuran / 110 °C / 73550.8 Torr

2: pyridine

With pyridine; dihydrogen hexachloroplatinate; trichlorosilane; In tetrahydrofuran; benzene;

Reference yield:

methanol (67-56-1) + 4-(2-trichlorosilylethyl)-1-cyclohexene (18290-60-3) → (2-(cyclohex-3-en-1-yl)ethyl)trimethoxysilane (67592-36-3)

Guidance literature:

With pyridine;

upstream raw materials:

methanol

4-(2-trichlorosilylethyl)-1-cyclohexene

4-ethenylcyclohexene

trimethoxysilane

Refernces