Benzene,1,1'-selenonylbis-

Base Information

• Chemical Name: Benzene,1,1'-selenonylbis-
• CAS No.: 10504-99-1
• Molecular Formula: C12H10 O2 Se
• Molecular Weight: 265.17
• Mol file: 10504-99-1.mol

Synonyms:Phenylselenone (6CI,7CI,8CI); Diphenyl selenone; NSC 243669

Chemical Property of Benzene,1,1'-selenonylbis-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene,1,1'-selenonylbis-

There total 7 articles about Benzene,1,1'-selenonylbis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diphenylselenoxide (7304-91-8) → diphenyl selenone (10504-99-1)

Guidance literature:

With dimethylsulfide; methylene blue; In dichloromethane; for 0.0833333h; Heating; photooxygenation;

DOI:10.1016/j.tetlet.2003.12.065

Reference yield:

diphenylselenide (1132-39-4) → diphenyl selenone (10504-99-1) + diphenylselenoxide (7304-91-8)

Guidance literature:

With acetonitrile complex of hypofluorous acid;

DOI:10.1002/ejoc.201300694

Reference yield:

Perbenzoic acid (93-59-4) + diphenylselenide (1132-39-4) → diphenyl selenone (10504-99-1)

Guidance literature:

With diethyl ether;

DOI:10.1007/s003300101021

upstream raw materials:

peracetic acid

diphenylselenide

Perbenzoic acid

diethyl ether

Downstream raw materials:

N-phenylsulfonyl-Se,Se-diphenylselenimide

N-p-Chlorbenzolsulfonyl-Se,Se-diphenylselenoximin

N-p-Nitrobenzolsulfonyl-Se,Se-diphenylselenoximin

N-p-Tolylsulfonyl-Se,Se-diphenylselenoximin

Refernces

• 1、 Sofikiti, Nikoletta,Rabalakos, Constantinos,Stratakis, Manolis. "Efficient trapping of the intermediates in the photooxygenation of sulfides by aryl selenides and selenoxides". . p. 1335 - 1337. Retrieved 2004.
• 2、 Khurana, Jitender M.,Kandpal, Bhaskar M.,Chauhan, Yogendra K.. "Rapid oxidation of selenides, selenoxides, tellurides, and telluroxides with aqueous sodium hypochlorite". . p. 1369 - 1375. Retrieved 2007/10/03.