Bis(dinitropropyl) formal

Base Information

• Chemical Name: Bis(dinitropropyl) formal
• CAS No.: 5917-61-3
• Deprecated CAS: 95327-32-5
• Molecular Formula: C7H12 N4 O10
• Molecular Weight: 312.193
• European Community (EC) Number: 611-807-8
• NSC Number: 312446
• DSSTox Substance ID: DTXSID0052255
• Nikkaji Number: J106.000G
• Wikidata: Q81976712
• Mol file: 5917-61-3.mol

Synonyms:Bis(dinitropropyl) formal;5917-61-3;BDNPF;Bis(2,2-dinitropropyl)formal;Bis(dinitropropyl)formal;Bis(2,2-dinitropropyl) formal;bis-(2,2-dinitropropyl)formal;Bis-(2,2-dinitropropyl) acetal formaldehyde;Methane, bis(2,2-dinitropropoxy)-;NSC 312446;BRN 1893228;Propane, 1,1'-(methylenebis(oxy))bis(2-nitro-;1,1'-(Methylenebis(oxy))bis(2,2-dinitropropane);Propane, 1,1'-(methylenebis(oxy))bis(2,2-dinitro-;Propane, 1,1'-[methylenebis(oxy)]bis[2,2-dinitro-;Methane,2-dinitropropoxy)-;SCHEMBL439564;Bis(2,2-dinitropropoxy)methane;DTXSID0052255;C7H12N4O10;NSC312446;C7-H12-N4-O10;NSC-312446;LS-120833;Propane,1'-[methylenebis(oxy)]bis[2-nitro-;Propane,1'-[methylenebis(oxy)]bis[2,2-dinitro-;1-[(2,2-Dinitropropoxy)methoxy]-2,2-dinitropropane

Chemical Property of Bis(dinitropropyl) formal

Chemical Property:

• Vapor Pressure: 2.63E-07mmHg at 25°C
• Refractive Index: 1.6700 (estimate)
• Boiling Point: 421.3°C at 760 mmHg
• Flash Point: 186.1°C
• PSA: 201.74000
• Density: 1.5g/cm³
• LogP: 1.60910
• XLogP3: 0.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 6
• Exact Mass: 312.05534259
• Heavy Atom Count: 21
• Complexity: 361

Purity/Quality:

99% ^*data from raw suppliers

BIS-(2,2-DINITROPROPYL)FORMAL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Uses -> Explosives
• Canonical SMILES: CC(COCOCC(C)([N+](=O)[O-])[N+](=O)[O-])([N+](=O)[O-])[N+](=O)[O-]

Technology Process of Bis(dinitropropyl) formal

There total 4 articles about Bis(dinitropropyl) formal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

→ bis(2,2-dinitropropyl)formal (5917-61-3,95327-32-5)

Guidance literature:

Reference yield:

bis(2-nitro-1-propyl)acetal (27911-85-9) + bis(2-nitro-1-propyl)formal (1184730-31-1) → bis(2,2-dinitropropyl)formal (5917-61-3,95327-32-5) + bis(2,2-dinitropropyl)acetal (5108-69-0,95327-31-4)

Guidance literature:

With sodium hydroxide; potassium hexacyanoferrate(III); sodium nitrite; In methanol; water; at 4 - 21 ℃; for 2h; Product distribution / selectivity;

Reference yield:

bis(2-nitro-1-propyl)formal (1184730-31-1) → bis(2,2-dinitropropyl)formal (5917-61-3,95327-32-5)

Guidance literature:

With sodium hydroxide; potassium hexacyanoferrate(III); sodium nitrite; In methanol; dichloromethane; water; at 5 - 25 ℃; Cooling with dry ice/methanol;

upstream raw materials:

formaldehyd

2,2-dinitropropanol

bis(2-nitro-1-propyl)formal

bis(2-nitro-1-propyl)acetal

Refernces

• 1、 -. "Synthesis of bis(2,2-dinitropropyl) formal (BDNPF)". . . Retrieved 2008/06/13.