(2,2'-Bipyridine)dichlorocopper

Base Information

• Chemical Name: (2,2'-Bipyridine)dichlorocopper
• CAS No.: 22393-36-8
• Molecular Formula: C₁₀H₈Cl₂CuN₂
• Molecular Weight: 290.639
• Mol file: 22393-36-8.mol

Synonyms:Copper,(2,2'-bipyridine)dichloro- (8CI); Copper, (2,2'-bipyridine-N,N')dichloro-;Copper, dichloro(2,2'-bipyridine)- (7CI); (2,2'-Bipyridine)dichlorocopper;(Bipyridine)copper dichloride; Dichloro(2,2'-bipyridine)copper; NSC 169940; RL5176

Chemical Property of (2,2'-Bipyridine)dichlorocopper

Chemical Property:

• Boiling Point: 311.4°Cat760mmHg
• Flash Point: 189.6°C
• PSA: 6.48000
• Density: g/cm³
• LogP: 2.87630

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,2'-Bipyridine)dichlorocopper

There total 14 articles about (2,2'-Bipyridine)dichlorocopper which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

[2,2]bipyridinyl (366-18-7) + copper(II) choride dihydrate → 2,2'-bipyridinedichlorocopper(II) (220632-01-9,22393-36-8)

Guidance literature:

In acetonitrile; equimolar amts.; elem. anal.;

DOI:10.1021/ic970819m

Reference yield: 71.56%

[2,2]bipyridinyl (366-18-7) + copper dichloride → 2,2'-bipyridinedichlorocopper(II) (220632-01-9,22393-36-8)

Guidance literature:

In ethanol;

DOI:10.14233/ajchem.2019.22018

Reference yield: 46.0%

[2,2]bipyridinyl (366-18-7) + oxygen (80937-33-3) + acetonitrile (75-05-8,26809-02-9) + copper(l) chloride → Cu(2,2'-bipyridyl)(oxalate) (1012367-93-9,26382-68-3) + 2,2'-bipyridinedichlorocopper(II) (220632-01-9,22393-36-8)

Guidance literature:

With 3,5-di-tert-butylcatechol; In acetonitrile; CuCl in the presence of 3,5-di-tert-butylcatechol or 3,5-di-tert-butyl-1,2-benzoquinone and 2,2'-bipyridine in CH3CN was reacted with O2; recrystn.;

DOI:10.1021/ic800745g

upstream raw materials:

[2,2]bipyridinyl

chloride

dicyandiamide

(2-13C)acetonitrile

Downstream raw materials:

[Cu(2,2'-bipyridine)(1,2-dithiosquarate)]

2,2'-bipyridine-1,2-dithiooxalatocopper(II)

Refernces

• 1、 Eremina, Julia A.,Lider, Elizaveta V.,Samsonenko, Denis G.,Sheludyakova, Liliya A.,Berezin, Alexey S.,Klyushova, Lyubov S.,Ostrovskii, Vladimir A.,Trifonov, Rostislav E.. "Mixed-ligand copper(II) complexes with tetrazole derivatives and 2,2′-bipyridine, 1,10-phenanthroline: Synthesis, structure and cytotoxic activity". . p. 138 - 144. Retrieved 2019/01/03.
• 2、 Casagrande, Gleison Ant?nio,Pires de Oliveira, Kelly Mari,Da Silva Dantas, Fabiana Gomes,De Almeida-Apolonio, Adriana Araújo,De Araújo, Renata Pires,Vizolli Favarin, Lis Regiane,De Castilho, Pamella Fukuda,De Oliveira Galv?o, Fernanda,Estivalet Svidzinski, Terezinha Inez. "A promising copper(II) complex as antifungal and antibiofilm drug against yeast infection". . . Retrieved 2018/08/04.