1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-iododecane

Base Information

• Chemical Name: 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-iododecane
• CAS No.: 2043-53-0
• Molecular Formula: C10H4F17I
• Molecular Weight: 574.019
• Hs Code.: 29037800
• European Community (EC) Number: 218-053-5
• DSSTox Substance ID: DTXSID6062123
• Nikkaji Number: J28.291J
• Wikidata: Q72481195
• Mol file: 2043-53-0.mol

Synonyms:2043-53-0;1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-iododecane;1-Iodo-1H,1H,2H,2H-perfluorodecane;1H,1H,2H,2H-Perfluorodecyl iodide;2-(perfluorooctyl)ethyl iodide;1H,1H,2H,2H-Heptadecafluorodecyl Iodide;1-Iodo-1,1,2,2-tetrahydroperfluorodecane;C10H4F17I;EINECS 218-053-5;1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-10-iodo-decane;Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-10-iodo-;1H,1H,2H,2H-Perfluoro-1-iododecane;68390-33-0;MFCD00039411;8:2 Fluorotelomer iodide;C8F17CH2CH2I;SCHEMBL969176;CF3(CF2)7CH2CH2I;DTXSID6062123;1-(Perfluorooctyl)-2-iodoethane;1h,1h,2h,2h-perfluorodecyliodide;C10 Gamma-Omega Perfluoro Iodine;2-(Heptadecafluorooctyl)ethyl iodide;C10-H4-F17-I;AKOS005063722;CS-W011449;MS-20459;1H,1H,2H,2H-Heptadecafluoro-1-iododecane;FT-0607941;H1084;1-Iodo-1H,1H,2H,2H-perfluorodecane, 96%;D91003;A814552;J-013317;1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8 heptadecafluor-10-iodo-decane;1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecakis(fluoranyl)-10-iodanyl-decane

Chemical Property of 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-iododecane

Chemical Property:

• Appearance/Colour: Tan solid.
• Vapor Pressure: 0.00109mmHg at 25°C
• Melting Point: 57-62 °C
• Refractive Index: 1.482
• Boiling Point: 178°C at 760 mmHg
• Flash Point: 100.8°C
• PSA: 0.00000
• Density: 1.879g/cm³
• LogP: 6.82090
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Light Sensitive
• Solubility.: Chloroform (Soluble), Methanol (Slightly)
• Water Solubility.: Insoluble in water.
• XLogP3: 7.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 17
• Rotatable Bond Count: 8
• Exact Mass: 573.90863
• Heavy Atom Count: 28
• Complexity: 559

Purity/Quality:

99% ^*data from raw suppliers

1H,1H,2H,2H-Heptadecafluorodecyl Iodide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(CI)C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Description: 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-10-iodoheptane is an organic fluorine fabric finishing agent. The organic fluorine fabric finishing agent has excellent water and oil repellency, air permeability and washing resistance, anti-fouling and easy decontamination properties.
• Uses: 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-iododecane is used in that preparation of a chemical compounds employed in high-performance organic thin-film transistors. It also finds it application as an appliance in boat and building paint.

Technology Process of 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-iododecane

There total 13 articles about 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-iododecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.3%

1-iodoheptadecafluorooctane (507-63-1) + ethene (74-85-1) → 2-(n-perfluorooctyl)ethyl iodide (2043-53-0,71215-70-8)

Guidance literature:

With dibenzoyl peroxide; at 85 ℃; for 5h;

DOI:10.1021/jm00347a012

Reference yield: 98.2%

1-iodoheptadecafluorooctane (507-63-1) + ethene (74-85-1) → 2-(n-perfluorooctyl)ethyl iodide (2043-53-0,71215-70-8) + 5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecyl iodide (38565-62-7)

Guidance literature:

at 160 ℃; for 8h;

DOI:10.1016/S0022-1139(03)00110-6

Reference yield: 89.0%

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) → 2-(n-perfluorooctyl)ethyl iodide (2043-53-0,71215-70-8)

Guidance literature:

With 1H-imidazole; iodine; triphenylphosphine; In diethyl ether; acetonitrile; at 20 ℃; for 19h;

DOI:10.1021/jo701349c

upstream raw materials:

1-iodoheptadecafluorooctane

ethene

sodium 4-methylbenzenesulfinate

trimethyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-iododecyl)silane

Downstream raw materials:

1H,1H,2H,2H-Perfluorodecanethiol

1-(4'-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecane

1H,1H,2H-perfluorodecene

2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyl)-malonic acid dimethyl ester

Refernces

• 1、 Fuchikami, Takamasa,Ojima, Iwao. "TRANSITION-METAL COMPLEX CATALYZED POLYFLUOROALKYLATION. I. FACILE ADDITION OF POLYFLUOROALKYL HALIDES TO CARBON-CARBON MULTIPLE BONDS". . p. 303 - 306. Retrieved 1984.
• 2、 Consorti, Crestina S.,Jurisch, Markus,Gladysz, John A.. "Ionic transformations in extremely nonpolar fluorous media: Phase transfer catalysis of halide substitution reactions". . p. 2309 - 2312. Retrieved 2008/02/05.
• 3、 Igumnov, Sergei M.,Don, Veronika L.,Vyazkov, Vladimir A.,Narinyan, Karen E.. "Copper salt-catalysed reaction of perfluoroalkyl halides with olefins". . p. 189 - 190. Retrieved 2007/10/03.