Fenamiphos sulfoxide

Base Information

• Chemical Name: Fenamiphos sulfoxide
• CAS No.: 31972-43-7
• Deprecated CAS: 124793-11-9
• Molecular Formula: C13H22 N O4 P S
• Molecular Weight: 319.362
• Hs Code.: 2931900090
• European Community (EC) Number: 634-805-9
• UNII: E9KC714FKU
• DSSTox Substance ID: DTXSID8037548
• Nikkaji Number: J152.215I
• Wikidata: Q27896416
• ChEMBL ID: CHEMBL1904448
• Mol file: 31972-43-7.mol

Synonyms:fenamiphos sulfoxide;fenamiphos sulphoxide

Chemical Property of Fenamiphos sulfoxide

Chemical Property:

• Boiling Point: 436.5°Cat760mmHg
• PKA: -0.34±0.70(Predicted)
• Flash Point: 217.8°C
• PSA: 93.65000
• Density: 1.22g/cm³
• LogP: 4.51040
• Storage Temp.: 2-8°C
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 7
• Exact Mass: 319.10071635
• Heavy Atom Count: 20
• Complexity: 377

Purity/Quality:

99% ^*data from raw suppliers

Fenamiphos sulfoxide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T+,N
• Statements: 28-50/53
• Safety Statements: 28-36/37-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCOP(=O)(NC(C)C)OC1=CC(=C(C=C1)S(=O)C)C
• Uses: A toxic metabolite of Fenamiphos, a pesticide in fruits and vegetables.

Technology Process of Fenamiphos sulfoxide

There total 2 articles about Fenamiphos sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

FENAMIPHOS (22224-92-6) → (1-methylethyl)phosphoramidic acid ethyl 3-methyl-4(methylsulfinyl)phenyl ester (31972-43-7,124793-11-9)

Guidance literature:

With perfluoro cis-2-n-butyl-3-n-propyloxaziridine; In various solvent(s); at 0 ℃; for 0.166667h; Yield given;

DOI:10.1016/0040-4020(95)00413-3

Reference yield:

3-methyl-4-(methylsulfinyl)phenol (14143-28-3) + isopropylamine (75-31-0) → (1-methylethyl)phosphoramidic acid ethyl 3-methyl-4(methylsulfinyl)phenyl ester (31972-43-7,124793-11-9)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1016/0040-4020(95)00413-3

Reference yield: 90.0%

(1-methylethyl)phosphoramidic acid ethyl 3-methyl-4(methylsulfinyl)phenyl ester (31972-43-7,124793-11-9) → (1-methylethyl)phosphoramidic acid ethyl 3-methyl-4(methylsulfonyl)phenyl ester (31972-44-8)

Guidance literature:

With perfluoro cis-2-n-butyl-3-n-propyloxaziridine; In various solvent(s); at 0 ℃; for 8h;

DOI:10.1016/0040-4020(95)00413-3

upstream raw materials:

FENAMIPHOS

3-methyl-4-(methylsulfinyl)phenol

isopropylamine

Downstream raw materials:

(1-methylethyl)phosphoramidic acid ethyl 3-methyl-4(methylsulfonyl)phenyl ester

Refernces