2-Norbornanethione, 1,3,3-trimethyl-

Base Information

• Chemical Name: 2-Norbornanethione, 1,3,3-trimethyl-
• CAS No.: 875-06-9
• Molecular Formula: C10H16S
• Molecular Weight: 168.303
• Hs Code.: 2930909090
• DSSTox Substance ID: DTXSID701007604
• Nikkaji Number: J100.326G
• Mol file: 875-06-9.mol

Synonyms:2-Norbornanethione, 1,3,3-trimethyl-;Thiofenchone;875-06-9;Bicyclo[2.2.1]heptane-2-thione, 1,3,3-trimethyl-;Fenchthione;1,3,3-Trimethylbicyclo[2.2.1]heptane-2-thione;SCHEMBL6950802;DTXSID701007604;1,3,3-Trimethylbicyclo[2.2.1]heptane-2-thione #

Chemical Property of 2-Norbornanethione, 1,3,3-trimethyl-

Chemical Property:

• Vapor Pressure: 0.265mmHg at 25°C
• Boiling Point: 211.5°Cat760mmHg
• Flash Point: 81.7°C
• PSA: 32.09000
• Density: 1.03g/cm³
• LogP: 3.20250
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 168.09727168
• Heavy Atom Count: 11
• Complexity: 217

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(C2CCC(C2)(C1=S)C)C

Technology Process of 2-Norbornanethione, 1,3,3-trimethyl-

There total 2 articles about 2-Norbornanethione, 1,3,3-trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

spiro[1,3,3-trimethyl-bicyclo[2.2.1]heptane-2,2'-(1',3'-dithiolane 1'-oxide)] (189510-52-9) → ethene (74-85-1) + 1,3,3-trimethyl-bicyclo[2.2.1]heptane-2-thione (875-06-9)

Guidance literature:

at 550 ℃; under 0.01 Torr; flash vacuum pyrolysis;

DOI:10.3891/acta.chem.scand.51-0527

Reference yield: 63.0%

spiro[1,3,3-trimethyl-bicyclo[2.2.1]heptane-2,2'-(1',3'-dithiolane 1'-oxide)] (189510-52-9) → ethene (74-85-1) + 1,3,3-trimethyl-bicyclo[2.2.1]heptane-2-thione (875-06-9)

Guidance literature:

at 800 ℃; under 0.01 Torr; Product distribution; flash vacuum pyrolysis; var. temp. 700 to 850;

DOI:10.3891/acta.chem.scand.51-0527

Reference yield: 93.0%

Thiofenchone (875-06-9,53402-11-2,54423-29-9) → (+/-)-fenchone (18492-37-0,126-21-6)

Guidance literature:

With polystyrene-bound diaryl telluroxide; In chloroform; for 3h; Ambient temperature;

DOI:10.1246/bcsj.59.879

upstream raw materials:

spiro[1,3,3-trimethyl-bicyclo[2.2.1]heptane-2,2'-(1',3'-dithiolane 1'-oxide)]

Downstream raw materials:

1,3,3-trimethyl-2-norbornanone

thiofenchone S-oxide

(+/-)-fenchone

(1,3,3-trimethyl-[2]norbornyliden)-aniline

Refernces