Silabenzene

Base Information

• Chemical Name: Silabenzene
• CAS No.: 289-77-0
• Molecular Formula: C5H6 Si
• Molecular Weight: 94.1881
• DSSTox Substance ID: DTXSID40893913
• Nikkaji Number: J679.062C
• Wikipedia: Silabenzene
• Wikidata: Q3290409
• Mol file: 289-77-0.mol

Synonyms:Silabenzene;289-77-0;DTXSID40893913;Q3290409

Chemical Property of Silabenzene

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.57630
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 94.023876726
• Heavy Atom Count: 6
• Complexity: 30.9

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=[SiH]C=C1

Technology Process of Silabenzene

There total 4 articles about Silabenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-sila-2,5-cyclohexadiene (81200-77-3) → cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) + silabenzene (289-77-0) + acetylene (74-86-2,25067-58-7)

Guidance literature:

at 800 ℃; under 1E-05 Torr;

Reference yield:

1,2-dihydrosiline (52023-17-3) → cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) + silabenzene (289-77-0) + acetylene (74-86-2,25067-58-7)

Guidance literature:

at 800 ℃; under 0.0001 Torr; Ar matrix isolation, 10 K;

Reference yield:

1,2-dihydrosiline (52023-17-3) → cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) + silabenzene (289-77-0)

Guidance literature:

at 200 - 1200 ℃; under 0.005 - 0.01 Torr; Product distribution; vacuum pyrolysis; other silacyclohexenes investigated;

DOI:10.1007/BF00955424

upstream raw materials:

1-sila-2,5-cyclohexadiene

1-Allyl-1-sila-2,4-cyclohexadien

1,2-dihydrosiline

Refernces

• 1、 Maier, Guenther,Mihm, Gerhard,Baumgaertner, Richard Otto Wilhelm,Reisenauer, Hans Peter. "Hetero-?-Systems, 7. Silabenzene". . p. 2337 - 2350. Retrieved 2007/10/02.
• 2、 Solouki, Bahman,Rosmus, Pavel,Bock, Hans,Maier, Guenther. "Kurzweg-Pyrolyse: Silabenzol". . p. 56 - 57. Retrieved 2007/10/02.