Biliverdin ixdelta dimethyl ester

Base Information

• Chemical Name: Biliverdin ixdelta dimethyl ester
• CAS No.: 26195-58-4
• Molecular Formula: C₃₅H₃₈N₄O₆
• Molecular Weight: 610.71
• Mol file: 26195-58-4.mol

Synonyms:12,17-diethenyl-1,19-23,24-tetrahydro-2,8,13,18-tetramethyl-1,19-dioxo-21H-biline-3,7-dipropanoic acid, dimethyl ester;biliverdin IX delta dimethyl ester;biliverdin IXdelta dimethyl ester

Chemical Property of Biliverdin ixdelta dimethyl ester

Chemical Property:

• XLogP3: 3.2
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 13
• Exact Mass: 610.27913494
• Heavy Atom Count: 45
• Complexity: 1570

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(C(=CC2=NC(=O)C(=C2CCC(=O)OC)C)NC1=CC3=C(C(=C(N3)C=C4C(=C(C(=O)N4)C)C=C)C)C=C)CCC(=O)OC
• Isomeric SMILES: CC\1=C(/C(=C/C2=NC(=O)C(=C2CCC(=O)OC)C)/N/C1=C/C3=C(C(=C(N3)/C=C\4/C(=C(C(=O)N4)C)C=C)C)C=C)CCC(=O)OC

Technology Process of Biliverdin ixdelta dimethyl ester

There total 2 articles about Biliverdin ixdelta dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + iron(III) protoporphyrin IX chloride (13496-05-4,16009-13-5) → biliverdin IXγ dimethyl ester (26280-00-2,21494-89-3) + δ-biliverdin-IX dimethyl ester (26195-58-4) + α-biliverdin-IX dimethyl ester (10035-62-8) + β-biliverdin-IX dimethyl ester

Guidance literature:

iron(III) protoporphyrin IX chloride; With ascorbic acid; In pyridine; aq. phosphate buffer; at 37 ℃; for 5h; pH=7;

methanol; With hydrogenchloride; at 4 ℃; for 16h;

DOI:10.1016/j.bbagen.2014.07.021

Reference yield:

→ biliverdin-IXα dimethyl ester (53735-24-3) + biliverdine (58416-08-3) + δ-biliverdin-IX dimethyl ester (26195-58-4) + biliverdin IXβ (84757-06-2)

Guidance literature:

With oxygen; ascorbic acid; Yield given. Multistep reaction; 1.) aq. pyridine; 2.) water;

DOI:10.1039/P19870000307

upstream raw materials:

methanol

iron(III) protoporphyrin IX chloride

Refernces

• 1、 Jackson, Anthony H.,Rao, K. R. Nagaraja,Wilkins,Martyn. "Synthetic and Biosynthetic Studies of Porphyrins.Part 11.The Synthesis of meso Oxygenated Protoporphyrins.". . p. 307 - 312. Retrieved 2007/10/02.