Bismuthine, tribromo-

Base Information

• Chemical Name: Bismuthine, tribromo-
• CAS No.: 7787-58-8
• Molecular Formula: BiBr3
• Molecular Weight: 448.692
• European Community (EC) Number: 232-121-1
• UNII: DT59198T2X
• DSSTox Substance ID: DTXSID8064850
• Wikipedia: Bismuth(III) bromide,Bismuth tribromide,Bismuth_tribromide
• Wikidata: Q2614358
• Mol file: 7787-58-8.mol

Synonyms:Bismuth(III) bromide;7787-58-8;Bismuth bromide;Bismuth tribromide;Bismuthine, tribromo-;tribromobismuthine;BiBr3;bismuth (III) bromide;UNII-DT59198T2X;DT59198T2X;tribromobismuthane;Bismuth(Ii)Bromide;EINECS 232-121-1;MFCD00014195;bismuth (III)bromide;Bi-Br3;BISMUTH BROMIDE [MI];BISMUTH BROMIDE (BIBR3);DTXSID8064850;Bismuth(III) bromide, >=98%;AKOS015915837;Bismuth(III) bromide, 99% (metals basis);CS-0160142;Q2614358;Bismuth(III) bromide anhydrous, 99,999% (metals basis);Bismuth(III) bromide, anhydrous, beads, 99.999% trace metals basis;Bismuth(III) bromide, anhydrous, powder, 99.999% trace metals basis

Chemical Property of Bismuthine, tribromo-

Chemical Property:

• Appearance/Colour: Light yellow-gray crystals or crystalline powder
• Melting Point: 218 °C
• Boiling Point: 453 °C
• Flash Point: 453°C
• PSA: 0.00000
• Density: 5.7 g/mL at 25 °C(lit.)
• LogP: 2.53680
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 447.73336
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: Br[Bi](Br)Br

Technology Process of Bismuthine, tribromo-

There total 36 articles about Bismuthine, tribromo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bismuth (7440-69-9) + bromine (7726-95-6) → bismuth(III) bromide (7787-58-8)

Guidance literature:

In melt; passing a stream of Br2/inert gas into molten Bi with formation of volatile BiBr3; description of the aparatus given;;

Reference yield: 100.0%

bismuth (7440-69-9) + iodine(I) bromide (7789-33-5) → bismuth(III) bromide (7787-58-8)

Guidance literature:

In melt;

DOI:10.1007/BF00899513

Reference yield:

carbon tetrabromide (558-13-4) + bismuth(III) oxide (1304-76-3) → bismuth oxobromide (7787-57-7) + bismuth(III) bromide (7787-58-8)

Guidance literature:

In neat (no solvent); byproducts: CO2, CO; heating Bi2O3 and CBr4 in vacuum at 200°C; various yields for various educt ratio;;

upstream raw materials:

bromine

bismuth(III) oxide

carbon tetrabromide

bismuth(III) nitrate

Downstream raw materials:

tris(4-bromophenyl)bismuthane

bismuth(III) fluoride

selenium tetrabromide

tris(pentafluorophenyl)bismuth

Refernces

• 1、 Muir,Eagles. "". . p. 90 - 90. Retrieved 1895.
• 2、 Filatova,Gurin,Kloo,Kulbachinskii,Kuznetsov,Kytin,Lindsjo,Popovkin. "Electronic structure, galvanomagnetic and magnetic properties of the bismuth subhalides Bi4I4 and Bi4Br4". . p. 1103 - 1109. Retrieved 2007.
• 3、 Guenther, Anja,Steden, Folker,Ruck, Michael. "Syntheses, crystal structures, and triple twinning of the cluster trimers Bi2[PtBi6Br12]3 and Bi 2[PtBi6I12]3". . p. 423 - 430. Retrieved 2008.
• 4、 Landers,Brill. "Structure and bonding in chloro- and bromobismuthate(III) clusters (BiX4-, Bi2X93-, BiX63-) by NQR spectroscopy". . p. 744 - 749. Retrieved 1980.
• 5、 Waters, Jordan B.,Chen, Qien,Everitt, Thomas A.,Goicoechea, Jose M.. "N-Heterocyclic carbene adducts of the heavier group 15 tribromides. Normal to abnormal isomerism and bromide ion abstraction". . p. 12053 - 12066. Retrieved 2017/09/25.