Ethylcarbamic acid phenyl ester

Base Information

• Chemical Name: Ethylcarbamic acid phenyl ester
• CAS No.: 17576-39-5
• Molecular Formula: C9H11 N O2
• Molecular Weight: 165.192
• Hs Code.: 2924299090
• Mol file: 17576-39-5.mol

Synonyms:Carbamicacid, ethyl-, phenyl ester (6CI,8CI,9CI); Phenyl N-ethylcarbamate

Chemical Property of Ethylcarbamic acid phenyl ester

Chemical Property:

• Vapor Pressure: 0.000124mmHg at 25°C
• Boiling Point: 334.9°Cat760mmHg
• Flash Point: 183.7°C
• PSA: 38.33000
• Density: 1.132g/cm³
• LogP: 2.18580

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethylcarbamic acid phenyl ester

There total 15 articles about Ethylcarbamic acid phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyl O‐(4‐nitrophenyl) carbonate (17175-11-0) + ethanamine hydrochloride (557-66-4) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + N-ethylcarbamicacid phenylester (17576-39-5)

Guidance literature:

With sodium hydroxide; In water; dimethyl sulfoxide; acetonitrile; at 25 ℃; Kinetics;

DOI:10.5012/bkcs.2013.34.6.1722

Reference yield:

3,4-dinitrophenyl phenyl carbonate (64897-41-2) + ethanamine hydrochloride (557-66-4) → N-ethylcarbamicacid phenylester (17576-39-5) + 3,4-dinitophenol (577-71-9)

Guidance literature:

With sodium hydroxide; In water; dimethyl sulfoxide; acetonitrile; at 25 ℃; Kinetics;

DOI:10.5012/bkcs.2013.34.6.1722

Reference yield:

phenyl p-cyanophenyl carbonate (17175-15-4) + ethanamine hydrochloride (557-66-4) → N-ethylcarbamicacid phenylester (17576-39-5) + 4-cyanophenol (767-00-0)

Guidance literature:

With sodium hydroxide; In water; dimethyl sulfoxide; acetonitrile; at 25 ℃; Kinetics;

DOI:10.5012/bkcs.2013.34.6.1722

upstream raw materials:

ethyl isocyanate

phenol

phenyl O‐(4‐nitrophenyl) carbonate

ethylamine

Downstream raw materials:

Chloromethyl-ethyl-carbamic acid phenyl ester

1-ethyl-3,7-dihydro-7-[(4-methoxyphenyl)methyl]-1H-purine-2,6-dione

4-(4-phenylbutyl)-N-ethyl-1-piperazinecarboxamide hydrochloride

N-(ethylcarbamoyl)-4-methylbenzenesulfonamide

Refernces

• 1、 Song, Yoon-Ju,Kim, Min-Young,Um, Ik-Hwan. "A kinetic study on ethylaminolysis of phenyl y-substituted-phenyl carbonates: Effect of leaving-group substituents on reactivity and reaction mechanism". . p. 1722 - 1726. Retrieved 2013/07/26.
• 2、 Oh, Hyuck Keun,Oh, Ji Young,Sung, Dae Dong,Lee, Ikchoon. "Aminolysis of aryl N-ethyl thionocarbamates: Cooperative effects of atom pairs O and S on the reactivity and mechanism". . p. 5624 - 5629. Retrieved 2007/10/03.