Disodium fumarate

Base Information

• Chemical Name: Disodium fumarate
• CAS No.: 17013-01-3
• Molecular Formula: C4H4 O4 . 2 Na
• Molecular Weight: 160.037
• Hs Code.: 2917 19 80
• European Community (EC) Number: 231-725-2,241-087-7
• UNII: 0578QTK490
• DSSTox Substance ID: DTXSID10168802
• Nikkaji Number: J69.686B
• Wikipedia: Sodium_fumarate
• Wikidata: Q836457
• Mol file: 17013-01-3.mol

Synonyms:(E)-2-butenedioic acid;2-butenedioic acid;ammonium fumarate;fumarate dianion;fumarate(2-);fumaric acid;Furamag;mafusol;magnesium fumarate;sodium fumarate

Chemical Property of Disodium fumarate

Chemical Property:

• Appearance/Colour: white
• Vapor Pressure: 5.19E-06mmHg at 25°C
• Melting Point: >300°C
• Boiling Point: 355.5 °C at 760 mmHg
• Flash Point: 183 °C
• PSA: 80.26000
• Density: g/cm³
• LogP: -2.95760
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Solubility.: 228g/l
• Water Solubility.: 228 g/L
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 159.97484710
• Heavy Atom Count: 10
• Complexity: 108

Purity/Quality:

98%,99%, ^*data from raw suppliers

Disodium Fumarate >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Acids, Metal Salts
• Canonical SMILES: C(=CC(=O)[O-])C(=O)[O-].[Na+].[Na+]
• Isomeric SMILES: C(=C/C(=O)[O-])\C(=O)[O-].[Na+].[Na+]
• Uses: Disodium Fumarate can be used to reduce or prevent dilution of target protein during recovery flush after filtration.

Technology Process of Disodium fumarate

There total 5 articles about Disodium fumarate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(dimethoxyphosphinothioyl)thio]-butanedioic acid, diethyl ester (121-75-5) → sodium O,O-dimethyl phosphorodithioate (26377-29-7) + ethanol (64-17-5) + fumaric acid disodium salt (17013-01-3)

Guidance literature:

With sodium hydroxide; Mechanism; Voltammetry of the reduction;

Reference yield:

maleic anhydride (108-31-6) → sodium maleate (3105-55-3,5873-57-4,7704-73-6,17013-01-3,18016-19-8,30915-61-8,44670-32-8,54060-75-2,72383-56-3,371-47-1) + maleic acid (110-16-7,26099-09-2)

Guidance literature:

With sodium hydroxide; In water;

Reference yield:

maleic anhydride (108-31-6) → sodium maleate (3105-55-3,5873-57-4,7704-73-6,17013-01-3,18016-19-8,30915-61-8,44670-32-8,54060-75-2,72383-56-3,371-47-1)

Guidance literature:

With water; sodium hydroxide; at 65 ℃;

DOI:10.14233/ajchem.2014.17659

upstream raw materials:

maleic anhydride

[(dimethoxyphosphinothioyl)thio]-butanedioic acid, diethyl ester

sodium maleate

(2E)-but-2-enedioic acid

Downstream raw materials:

(3-Phenyl-propylmercapto)-bernsteinsaeure

sodium succinate

disodium L-malate

benzoic acid anhydride

Refernces

• 1、 Khullar, Sadhika,Mandal, Sanjay K.. "Construction of diverse supramolecular assemblies of dimetal subunits differing in coordinated water molecules via strong hydrogen bonding interactions: Synthesis, crystal structures and spectroscopic properties". . p. 1515 - 1523. Retrieved 2014.
• 2、 Liu, Xinhua,Wang, Wenjing,Tong, Xinjia,Ding, Yunfei,Zhao, Xinqiang,Su, Hong. "Study of corrosion and scale inhibition of polyepoxysuccinic acid derivative". . p. 7716 - 7720. Retrieved 2015/02/02.