CID 16211608

Base Information

• Chemical Name: CID 16211608
• CAS No.: 15321-51-4
• Molecular Formula: C9Fe2 O9
• Molecular Weight: 372.689
• Hs Code.: 29310099
• DSSTox Substance ID: DTXSID50934700
• Mol file: 15321-51-4.mol

Synonyms:

Chemical Property of CID 16211608

Chemical Property:

• Appearance/Colour: gold
• Vapor Pressure: 3460mmHg at 25°C
• Melting Point: 100 °C
• Boiling Point: 209°C (rough estimate)
• PSA: 51.21000
• Density: 2,85 g/cm³
• LogP: -0.63800
• Storage Temp.: 2-8°C
• Sensitive.: Air Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 0
• Exact Mass: 366.847578
• Heavy Atom Count: 20
• Complexity: 169

Purity/Quality:

99% ^*data from raw suppliers

Iron nonacarbonyl, 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): FT
• Hazard Codes: F,T
• Statements: 11-23/25
• Safety Statements: 16-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [CH-]=O.[CH-]=O.[CH-]=O.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Fe].[Fe+3]
• Description: This carbonyl is obtained as dark yellow platelets by exposing solutions of the pentacarbonyl in organic solvents to sunlight or ultraviolet irradiation.
• Uses: It is an important reagent in organometallic chemistry and of occasional use in organic synthesis. Reacts with phenylsilanes to give triply bridged diiron complexes.

Technology Process of CID 16211608

There total 30 articles about CID 16211608 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

iron pentacarbonyl (13463-40-6,37220-42-1) → diiron nonacarbonyl (15321-51-4)

Guidance literature:

With acetic anhydride; In acetic acid; Irradiation (UV/VIS); irradiation using quartz Schlenk tube and rayonet RS photochemical reactor (λmax = 2500 ?), cooling react. mixt. with continuous stream of air; filtration, washing with water, ethanol, ether, and subsequently drying in vacuo;

DOI:10.1016/S0020-1693(01)00692-2

Reference yield: 53.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + (9,9-dimethylxanthene-4,5-diyl)-bis(dimethylsilane) (226943-15-3) → diiron nonacarbonyl (15321-51-4) + cis-[Fe(4,5-bis(dimethylsilyl)-9,9-dimethylxanthene(2-))(CO)4] (960063-94-9)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); under inert atm. soln. Fe(CO)5 and ligand in CH2Cl2 was irradiated undermedium-pressure Hg lamp (450 W) for 5 h; soln. was filtered, concd. and subjected to column chromy. on silica, solvent was evapd.; elem. anal.;

DOI:10.1021/om700720s

Reference yield: 23.0%

N,N,N,N,N,N-hexamethylphosphoric triamide (680-31-9) + iron pentacarbonyl (13463-40-6,71564-23-3,37220-42-1) + tris-(trimethylsilyl)silane (1873-77-4) → diiron nonacarbonyl (15321-51-4) + bis(trimethylsilyl)silanediyltricarbonylhydrido(trimethylsilyl)iron hexamethylphosphoramide complex + 2,2,3,3-tetrakis(trimethylsilyl)hexamethyltetrasilane (5181-43-1)

Guidance literature:

In hexane; byproducts: H2, CO; Irradiation (UV/VIS); quartz ampule, Fe- and Si-compd. dissoln., stirring by rotation, coolingwith air, medium pressure Hg lamp, mixture filtration, soln. of P-compd . addn.; bottom layer sepn., washing (hexane), residual solvent removing (reducedpressure), residue dissoln. in diethyl ether, cooling (-10°C); G C, HPLC, elem. anal.;

upstream raw materials:

iron pentacarbonyl

cyclohexane

water

triiron dodecarbonyl

Downstream raw materials:

iron

acetylferrocene

vinyl ferrocene

iron pentacarbonyl

Refernces

• 1、 Cowley,Kemp,Wilburn. "Reaction of (chlorophosphine)iron tetracarbonyl complexes with aluminum chloride. Iron tetracarbonyl complexes of two-coordinate phosphorus cations". . p. 4289 - 4293. Retrieved 1981.
• 2、 Kovalenko,Mitkina,Geras'Ko,Samsonenko,Naumov,Fedin. "Cucurbit[8]uril-based inclusion compounds containing iron(II), cobalt(III), and nickel(II) complexes with cyclam and cyclen as guest molecules: Synthesis and crystal structures". . p. 161 - 167. Retrieved 2011.
• 3、 Narbel et al.. "". . p. 161. Retrieved 1979.
• 4、 Warburg, O.. "". . p. 856 - 856. Retrieved 1928.
• 5、 Ringenberg, Mark R.,Schwilk, Max,Wittkamp, Florian,Apfel, Ulf-Peter,Kaim, Wolfgang. "Organometallic Fe–Fe Interactions: Beyond Common Metal–Metal Bonds and Inverse Mixed-Valent Charge Transfer". . p. 1770 - 1774. Retrieved 2017.
• 6、 Minglana, Jim Josephus G.,Okazaki, Masaaki,Hasegawa, Kenji,Luh, Lung-Shiang,Yamahira, Nobukazu,Komuro, Takashi,Ogino, Hiroshi,Tobita, Hiromi. "Iron, ruthenium, and osmium complexes supported by the bis(silyl) chelate ligand (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl): Synthesis, characterization, and reactivity". . p. 5859 - 5866. Retrieved 2008/10/09.