Diazene, bis(2,4,6-trinitrophenyl)-

Base Information

• Chemical Name: Diazene, bis(2,4,6-trinitrophenyl)-
• CAS No.: 19159-68-3
• Molecular Formula: C12H4 N8 O12
• Molecular Weight: 452.21
• Hs Code.: 2927000090
• European Community (EC) Number: 242-850-7
• DSSTox Substance ID: DTXSID0066458
• Nikkaji Number: J224.868I
• Mol file: 19159-68-3.mol

Synonyms:Diazene, bis(2,4,6-trinitrophenyl)-;19159-68-3;2,2',4,4',6,6'-Hexanitroazobenzene;Hexanitroazoxy benzene;bis(2,4,6-trinitrophenyl)diazene;EINECS 242-850-7;Diazene, 1,2-bis(2,4,6-trinitrophenyl)-;Hexanitroazoxy benzene [Forbidden];SCHEMBL8022143;DTXSID0066458;C12H4N8O12;C12-H4-N8-O12

Chemical Property of Diazene, bis(2,4,6-trinitrophenyl)-

Chemical Property:

• Boiling Point: 699.5°Cat760mmHg
• Flash Point: 376.9°C
• PSA: 299.64000
• Density: 2.15g/cm³
• LogP: 6.69040
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 2
• Exact Mass: 451.99486759
• Heavy Atom Count: 32
• Complexity: 716

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Uses -> Explosives
• Canonical SMILES: C1=C(C=C(C(=C1[N+](=O)[O-])N=NC2=C(C=C(C=C2[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-]

Technology Process of Diazene, bis(2,4,6-trinitrophenyl)-

There total 6 articles about Diazene, bis(2,4,6-trinitrophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

2,2-diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl (147506-92-1,1898-66-4) → tetraphenylhydrazine (632-52-0) + N-Pikryl-4-aminodiphenylamin (23250-43-3) + dipicryl-diazene (19159-68-3)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 20 ℃; Mechanism; Product distribution; Kinetics;

Reference yield:

2,4,6-trinitrochlorobenzene (88-88-0) → dipicryl-diazene (19159-68-3)

Guidance literature:

Multi-step reaction with 2 steps

1: alcohol; hydrazine hydrate

2: nitric acid

With ethanol; nitric acid; hydrazine hydrate;

Reference yield:

2,2',4,4',6,6'-hexanitrohydrazobenzene (68683-32-9) → dipicryl-diazene (19159-68-3)

Guidance literature:

With nitric acid;

upstream raw materials:

2,2',4,4',6,6'-hexanitrohydrazobenzene

2,2-diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl

nitric acid

acetic acid

Downstream raw materials:

potassium cyanide

2,4,6-Trinitrophenol

2,2',4,4',6,6'-hexanitrohydrazobenzene

2,4,6-trinitro-N-(m-tolyl)aniline

Refernces