Hexadec-11-enyl acetate

Base Information

• Chemical Name: Hexadec-11-enyl acetate
• CAS No.: 34010-21-4
• Molecular Formula: C18H34 O2
• Molecular Weight: 282.467
• Hs Code.: 2915390090
• European Community (EC) Number: 251-791-6
• Wikidata: Q104945686,Q104945687
• Mol file: 34010-21-4.mol

Synonyms:(Z)-Hexadec-11-enyl acetate;hexadec-11-enyl acetate;FT-0639147

Chemical Property of Hexadec-11-enyl acetate

Chemical Property:

• Vapor Pressure: 4.93E-05mmHg at 25°C
• Refractive Index: 1.4532 (20℃)
• Boiling Point: 348.7°Cat760mmHg
• Flash Point: 88.4°C
• PSA: 26.30000
• Density: 0.875g/cm³
• LogP: 5.80680
• Storage Temp.: -20°C
• Solubility.: Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
• XLogP3: 6.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 15
• Exact Mass: 282.255880323
• Heavy Atom Count: 20
• Complexity: 234

Purity/Quality:

98%,99%, ^*data from raw suppliers

(Z)-11-Hexadecen-1-olAcetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC=CCCCCCCCCCCOC(=O)C
• Uses: (Z)-11-Hexadecen-1-ol Acetate can be used to synthesize sex attractant compounds for insects such as Plutella Xylostella.

Technology Process of Hexadec-11-enyl acetate

There total 91 articles about Hexadec-11-enyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.5%

(Z)-11-hexadecen-1-ol (56683-54-6) + acetyl chloride (75-36-5) → (Z)-11-hexadecen-1-yl acetate (34010-21-4)

Guidance literature:

With pyridine; In benzene; for 4h; Heating;

Reference yield: 98.0%

(Z)-11-hexadecen-1-ol (56683-54-6) + acetic anhydride (108-24-7) → (Z)-11-hexadecen-1-yl acetate (34010-21-4)

Guidance literature:

With pyridine; for 12h; Ambient temperature;

DOI:10.1007/BF00629847

Reference yield: 90.0%

(Z)-11-hexadecenal (53939-28-9) + acetic anhydride (108-24-7) → (Z)-11-hexadecen-1-yl acetate (34010-21-4)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃;

upstream raw materials:

1-acetoxy-7-bromoheptane

(Z)-4-nonenyl bromide

(Z)-11-hexadecen-1-ol

acetic anhydride

Downstream raw materials:

(Z)-11-hexadecen-1-ol

(Z)-11-tetradecenyl acetate

(E)-tetradec-11-en-1-yl acetate

(Z)-11-hexadecenal

Refernces

• 1、 Zarbin, Paulo H. G.,Lorini, Lisete M.,Ambrogi, Bianca G.,Vidal, Diogo M.,Lima, Eraldo R.. "Sex pheromone of Lonomia obliqua: Daily rhythm of production, identification, and synthesis". . p. 555 - 565. Retrieved 2007.
• 2、 Le, Van-Dung,Le, T. Cam-Huong,Chau, Van-Trung,Le, T. Ngoc-Duyen,Dang, Chi-Hien,Vo, T. To-Nguyen,Nguyen, Trinh Duy,Nguyen, Thanh-Danh. "Palladium nanoparticlesin situsynthesized onCyclea barbatapectin as a heterogeneous catalyst for Heck coupling in water, the reduction of nitrophenols and alkynes". . p. 4746 - 4755. Retrieved 2021/03/22.
• 3、 -. "A moth pheromone pickles preparation method (by machine translation)". Paragraph 0026. . Retrieved 2019/05/15.