(6Z)-6-[(ethylamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1)

Base Information

• Chemical Name: (6Z)-6-[(ethylamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1)
• CAS No.: 14096-19-6
• Molecular Formula: C₁₈H₂₀CuN₂O₂
• Molecular Weight: 359.915
• Mol file: 14096-19-6.mol

Synonyms:

Chemical Property of (6Z)-6-[(ethylamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1)

Chemical Property:

• Vapor Pressure: 0.00717mmHg at 25°C
• Boiling Point: 269.6°Cat760mmHg
• Flash Point: 118.8°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (6Z)-6-[(ethylamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1)

There total 50 articles about (6Z)-6-[(ethylamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

H-Sal-N-Et (5961-36-4,443991-27-3) + copper(II) acetate hydrate → bis(N-ethylsalicylaldiminato)copper(II) (14096-19-6,26194-23-0)

Guidance literature:

In ethanol; to soln. of ligand in EtOH was added soln. of metal acetate in EtOH; mixt. refluxed for 2 h; cooled; ppt. filtered off; recrystd. (CHCl3/EtOH, 1:2); dried (vac.); elem. anal.;

DOI:10.1134/S0020168511080164

Reference yield:

{Cusal2} (14523-25-2,43190-54-1,86195-53-1) + ethylamine (75-04-7,85404-22-4) → {Cu(C6H4(O)CHNCH2CH3)2} (26194-23-0,14096-19-6)

Guidance literature:

In ethanol; reflux;; recrystn. from CHCl3-alc.;;

DOI:10.1021/ja01489a014

Reference yield:

H-Sal-N-Et (5961-36-4,443991-27-3) + bis(N-tert-butylsalicylaldiminato)copper(II) (13986-34-0,36508-99-3,36748-28-4) → bis(N-ethylsalicylaldiminato)copper(II) (14096-19-6,26194-23-0)

Guidance literature:

In methanol; nitromethane; byproducts: N-t-butylsalicylideneimine; at 25°C; monitored by stopped-flow spectrophotometry; Kinetics;

DOI:10.1016/S0020-1693(00)88956-2

upstream raw materials:

bis-salicylaldehyde copper(II)

ethylamine

H-Sal-N-Et

trans-[bis(N-ethyl-5-methyl-salicylaldiminato)copper(II)]

Refernces

• 1、 Elias, Horst,Muth, Horst,Niederhoefer, Beate,Wannowius, Klaus J.. "Ligand Substitution in Bis(N-alkylsalicylideneiminato)copper(II) Complexes: Comparison of Activation and Transfer Data obtained from Solvent Mixtures". . p. 1825 - 1830. Retrieved 1981.
• 2、 Pomogailo,Burlov,Golubeva,Petrova,Mashchenko,Pomogailo,Dzhardimalieva,Garnovskii. "Preparation of nanostructured materials through thermolysis of metal chelate complexes". . p. 876 - 883. Retrieved 2011.
• 3、 Garnovskii,Burlov,Lysenko,Garnovskii,Borodkina,Ponomarenko,Chigarenko,Nikolaevskii,Minkin. "Tribochemically active chelate complexes of salicylideneimines". . p. 120 - 127. Retrieved 2009/07/10.
• 4、 Elias, Horst,Froehn, Uwe,Giegerich, Gabriele,Stenger, Monika,Wannowius, Klaus J.. "Kinetics of Ligand Substitution in Bis(N-t-butylsalicylideneiminato)-copper(II): Aprotic Organic Solvents as Media". . p. 577 - 582. Retrieved 2007/10/02.