3-METHOXYCYCLOHEXENE

Base Information

• Chemical Name: 3-METHOXYCYCLOHEXENE
• CAS No.: 4845-04-9
• Molecular Formula: C7H12 O
• Molecular Weight: 112.172
• Mol file: 4845-04-9.mol

Synonyms:(1-Cyclohexen-1-yl)methanol;(Cyclohexenyl)methanol; 1-(Hydroxymethyl)-1-cyclohexene; 1-Cyclohexenemethanol;1-Cyclohexenylmethanol; NSC 249806

Chemical Property of 3-METHOXYCYCLOHEXENE

Chemical Property:

• Vapor Pressure: 0.16mmHg at 25°C
• Boiling Point: 189°Cat760mmHg
• Flash Point: 82.8°C
• PSA: 20.23000
• Density: 0.964g/cm³
• LogP: 1.47910

Purity/Quality:

99%min ^*data from raw suppliers

1-Cyclohexenemethanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1-Cyclohexenemethanol is a volatile component isolated from Eucalyptus species.

Technology Process of 3-METHOXYCYCLOHEXENE

There total 51 articles about 3-METHOXYCYCLOHEXENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methyl cyclohex-1-ene-1-carboxylate (18448-47-0) → 1-cyclohexene-1-methanol (4845-04-9)

Guidance literature:

With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 1h;

Reference yield: 99.0%

1-cyclohexene-1-carboxaldehyde (1192-88-7) → 1-cyclohexene-1-methanol (4845-04-9)

Guidance literature:

With diisobutylaluminium hydride; In dichloromethane;

DOI:10.1002/chem.200401065

Reference yield: 95.0%

4-Bromo-1-oxa-spiro[2.5]octane → 1-cyclohexene-1-methanol (4845-04-9)

Guidance literature:

With samarium diiodide; In tetrahydrofuran; at -78 ℃; for 0.166667h;

DOI:10.1055/s-1998-1889

upstream raw materials:

1-oxaspiro(2.5)octane

methyl cyclohex-1-ene-1-carboxylate

(2-chloro-cyclohexyl)-methanol

cyclohex-1-enecarboxylic acid ethyl ester

Downstream raw materials:

1-cyclohexen-1-ylmethyl acetate

cyclohex-1-en-1-ylmethyl phenylcarbamate

<(1-cyclohexenylcarbinyl)oxy>acetone

1-(Cyclohex-1-enylmethoxy)-silinane

Refernces

• 1、 Sato, Kazuto,Tanino, Keiji. "Synthetic Studies on Cyclocitrinol: Construction of the ABC Ring System Based on Epoxy-Nitrile Cyclization". supporting information. p. 674 - 678. Retrieved 2021/01/21.
• 2、 Amado, Patrícia S. M.,Coelho, Jaime A. S.,Cristiano, Maria L. S.,Frija, Luís M. T.,O'neill, Paul M.. "Synthesis of Non-symmetrical Dispiro-1,2,4,5-Tetraoxanes and Dispiro-1,2,4-Trioxanes Catalyzed by Silica Sulfuric Acid". . p. 10608 - 10620. Retrieved 2021/07/31.