2-Chloro-2-(trifluoromethyl)perfluoropentane

Base Information

• Chemical Name: 2-Chloro-2-(trifluoromethyl)perfluoropentane
• CAS No.: 67437-97-2
• Molecular Formula: C6ClF13
• Molecular Weight: 354.498
• Hs Code.: 2914199090
• European Community (EC) Number: 820-582-7
• DSSTox Substance ID: DTXSID80371528
• Wikidata: Q81985756
• Mol file: 67437-97-2.mol

Synonyms:67437-97-2;2-Chloro-2-(trifluoromethyl)perfluoropentane;2-chloro-1,1,1,3,3,4,4,5,5,5-decafluoro-2-(trifluoromethyl)pentane;2-Chloro(perfluoro-2-methylpentane);(2-Chloro)decafluoro-2-(trifluoromethyl)pentane;SCHEMBL10346621;DTXSID80371528;NTLNMNNHUJOUOM-UHFFFAOYSA-N;2-chloro-perfluoro-2-methylpentane;MFCD00153741;AKOS007930353;FT-0604614;A835751

Chemical Property of 2-Chloro-2-(trifluoromethyl)perfluoropentane

Chemical Property:

• Vapor Pressure: 80.1mmHg at 25°C
• Boiling Point: 83-84oC
• Flash Point: 23oC
• PSA: 0.00000
• Density: 1.687g/cm3
• LogP: 4.92150
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 13
• Rotatable Bond Count: 2
• Exact Mass: 353.9480938
• Heavy Atom Count: 20
• Complexity: 343

Purity/Quality:

99% ^*data from raw suppliers

2-Chloro-2-(trifluoromethyl)perfluoropentane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(F)(F)F)(F)F)(F)F)(C(F)(F)F)(C(F)(F)F)Cl

Technology Process of 2-Chloro-2-(trifluoromethyl)perfluoropentane

There total 4 articles about 2-Chloro-2-(trifluoromethyl)perfluoropentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

perfluoro-2-methylpent-2-ene (1584-03-8) → 2-perfluoromethyl-2-chloroperfluoropentane (67437-97-2)

Guidance literature:

With Iodine monochloride; cesium fluoride; In sulfolane; at 90 ℃; for 3h;

DOI:10.1007/BF00962467

Reference yield:

perfluoro-2-methylpent-1-ene (359-72-8) → 2-perfluoromethyl-2-chloroperfluoropentane (67437-97-2)

Guidance literature:

With chlorine monofluoride; at -10 ℃;

DOI:10.1134/S1070427213030154

Reference yield:

1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane (30320-28-6) → 2-perfluoromethyl-2-chloroperfluoropentane (67437-97-2)

Guidance literature:

With chlorine; triethylamine;

upstream raw materials:

1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane

perfluoro-2-methylpent-2-ene

perfluoro-2-methylpent-1-ene

Downstream raw materials:

perfluoro-2-methylpent-1-ene

perfluoro-2-methylpent-2-ene

Refernces

• 1、 Fenichev,Babenko,Bispen,Moldavskii. "Development of technology of perfluoroethyl isopropyl ketone production". . p. 376 - 386. Retrieved 2013/07/05.