Aldoxycarb

Base Information

• Chemical Name: Aldoxycarb
• CAS No.: 1646-88-4
• Deprecated CAS: 60005-95-0
• Molecular Formula: C7H14 N2 O4 S
• Molecular Weight: 222.265
• Hs Code.: 2930909052
• European Community (EC) Number: 216-710-0
• UN Number: 2757,3082
• UNII: IL70ANS043
• DSSTox Substance ID: DTXSID50859666
• ChEMBL ID: CHEMBL2138916
• Mol file: 1646-88-4.mol

Synonyms:aldicarb sulfone;aldoxycarb;Temik sulfone

Chemical Property of Aldoxycarb

Chemical Property:

• Vapor Pressure: 1.2×10-2 Pa (25 °C)
• Melting Point: 132-135 °C
• Refractive Index: 1.495
• Boiling Point: °Cat760mmHg
• PKA: 13.44±0.46(Predicted)
• Flash Point: °C
• PSA: 93.21000
• Density: 1.23g/cm³
• LogP: 1.62310
• Storage Temp.: 0-6°C
• Solubility.: DMSO (Slightly), Methanol (Slightly)
• Water Solubility.: 10 g l-1 (25 °C)
• XLogP3: -0.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 222.06742811
• Heavy Atom Count: 14
• Complexity: 326
• Transport DOT Label: Poison

Purity/Quality:

99.9% ^*data from raw suppliers

Aldicarb-sulfone PESTANAL ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T+
• Statements: 24-26/28
• Safety Statements: 28-36/37-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Carbamate Insecticides
• Canonical SMILES: CC(C)(C=NOC(=O)NC)S(=O)(=O)C
• Isomeric SMILES: CC(C)(/C=N/OC(=O)NC)S(=O)(=O)C
• Description: Aldoxycarb, is also called 2-mesyl-2-methylpropionaldehyde O-methylcarbamoyloxime (IUPAC), the sulfone analog of aldicarb, is also a systemic insecticide effective for control of insects (mainly sucking insect pests such as aphids, leafhoppers, etc.).
• Uses: Aldoxycarb is a soil applied systemic oxime carbamate insecticide effective for the control of insects (mainly sucking pests such as aphids, leafhoppers, etc.), mites and nematodes on many field (cotton, maize, etc.) and vegetable crops. Aldicarb Sulfone is an analog of Aldicarb (A514650) detected in agricultural products as pesticide residue.

Technology Process of Aldoxycarb

There total 3 articles about Aldoxycarb which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aldicarb (61602-66-2) → 2-methyl-2-(methylsulfonyl)propionaldehyde O-(methylcarbamoyl)oxime (1646-88-4)

Guidance literature:

With formic acid; sulfuric acid; dihydrogen peroxide; In dichloromethane; water;

Reference yield:

temik (116-06-3) → aldoxycarb (1646-88-4)

Guidance literature:

With peracetic acid; molybdenyl acetonylacetonate; In benzene; at 20 ℃; for 24h;

Reference yield:

→ aldoxycarb (1646-88-4)

Guidance literature:

Carbamyloxim XII, Peressigsaeure;

DOI:10.1021/jf60146a007

upstream raw materials:

temik

aldicarb

Downstream raw materials:

methylamine

Refernces

• 1、 -. "Preparation of organic sulfone compounds". . . Retrieved 2008/06/13.