Phenanthridine, 6-phenyl-

Base Information

• Chemical Name: Phenanthridine, 6-phenyl-
• CAS No.: 2720-93-6
• Molecular Formula: C19H13 N
• Molecular Weight: 255.319
• NSC Number: 40941
• DSSTox Substance ID: DTXSID90181675
• Nikkaji Number: J962.649B
• Wikidata: Q83052301
• Mol file: 2720-93-6.mol

Synonyms:6-phenylphenanthridine;2720-93-6;Phenanthridine, 6-phenyl-;6-phenylphenanthridin;6-PHENYL-PHENANTHRIDINE;NSC40941;Phenanthridine,6-phenyl-;SCHEMBL729919;DTXSID90181675;NSC 40941;NSC-40941;AKOS015951001

Chemical Property of Phenanthridine, 6-phenyl-

Chemical Property:

• Vapor Pressure: 3.55E-07mmHg at 25°C
• Melting Point: 105-106 °C
• Boiling Point: 429.3°Cat760mmHg
• PKA: 4.52±0.30(Predicted)
• Flash Point: 189.4°C
• PSA: 12.89000
• Density: 1.181g/cm³
• LogP: 5.05500
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 255.104799419
• Heavy Atom Count: 20
• Complexity: 320

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=NC3=CC=CC=C3C4=CC=CC=C42

Technology Process of Phenanthridine, 6-phenyl-

There total 143 articles about Phenanthridine, 6-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N-(2-iodophenyl)-1,1-diphenylmethanimine (1027223-93-3) → 6-phenylphenanthridine (2720-93-6)

Guidance literature:

With palladium diacetate; caesium carbonate; tricyclohexylphosphine; In tetrahydrofuran; at 110 ℃; for 24h; Inert atmosphere;

DOI:10.1021/jo2017108

Reference yield: 99.0%

9-phenyl-fluoren-9-ol (25603-67-2) → 6-phenylphenanthridine (2720-93-6)

Guidance literature:

With sodium azide; trifluoroacetic acid; at 20 ℃; for 3h; Inert atmosphere; Schlenk technique;

Reference yield: 99.0%

phenanthridine (229-87-8) + diphenylzinc (1078-58-6) → 6-phenylphenanthridine (2720-93-6)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel⁽⁰⁾; tricyclohexylphosphine; In toluene; at 60 ℃; for 20h;

DOI:10.1021/ja9053509

upstream raw materials:

pyridine

chloro-(9-phenyl-fluoren-9-yl)-amine

sodium methylate

phenanthridine

Downstream raw materials:

2-phenyl-3,4-benzoquinoline N-oxide

6,6'-diphenyl-5',6'-dihydro-[4,6']biphenanthridinyl

6,6-diphenyl-5,6-dihydro-phenanthridine

5-methyl-6-phenyl-phenanthridinium; methyl sulfate

Refernces

• 1、 -. "Method for rapidly synthesizing phenanthridine compounds". Paragraph 0015-0016; 0045-0049. . Retrieved 2021/08/19.
• 2、 Yang, Shan,Hong, Biqiong,Feng, Jia,Gu, Zhenhua. "Construction of 2-Amino-2′-ketonyl Biaryls via Acid-Mediated Ring Opening of 9 H-Fluoren-9-ols with Organic Azides". supporting information. p. 9179 - 9183. Retrieved 2021/11/30.