Tetraisopropylthiuram disulfide

Base Information

• Chemical Name: Tetraisopropylthiuram disulfide
• CAS No.: 4136-91-8
• Molecular Formula: C14H28N2S4
• Molecular Weight: 352.654
• Hs Code.: 29303000
• European Community (EC) Number: 625-528-4
• NSC Number: 40802
• UNII: V3H0EJ3KXW
• DSSTox Substance ID: DTXSID70194309
• Nikkaji Number: J116.884C
• Wikidata: Q83067074
• ChEMBL ID: CHEMBL4760573
• Mol file: 4136-91-8.mol

Synonyms:disulfide, bis(diisopropylthiocarbamoyl);N,N,N',N'-tetraisopropylthiuram disulfide;RI177;tetra-isopropylthiuram disulfide;tetraisopropylthiuram disulfide;thioperoxydicarbonic diamide (((H2N)C(S))2S2), N,N,N',N'-tetrakis(1-methylethyl)-;thioperoxydicarbonic diamide (((H2N)C(S))2S2), tetrakis(1-methylethyl)-

Chemical Property of Tetraisopropylthiuram disulfide

Chemical Property:

• Vapor Pressure: 0.000503mmHg at 25°C
• Melting Point: 115oC
• Boiling Point: 408.5°Cat760mmHg
• PKA: 0.75±0.50(Predicted)
• Flash Point: 200.8°C
• PSA: 121.26000
• Density: 1.124g/cm³
• LogP: 5.17520
• Solubility.: chloroform: soluble2.5%, clear, yellow
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 7
• Exact Mass: 352.11353360
• Heavy Atom Count: 20
• Complexity: 279

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetraisopropylthiuram Disulfide >98.0%(N) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)N(C(C)C)C(=S)SSC(=S)N(C(C)C)C(C)C
• Uses: Tetraisopropylthiuram disulphide has been used:for incorporation of a thiol equivalent into heterocyclic compounds, by reaction with appropriate lithiated heterocyclein preparation of unsymmetrical sulfidesas extractant for silver (I) extraction from photographic fixing solution Rubber accelerator.

Technology Process of Tetraisopropylthiuram disulfide

There total 5 articles about Tetraisopropylthiuram disulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium N,N'-diisopropyldithiocarbamate (4092-82-4) + C22H28N2S4 → tetraisopropylothiuram disulphide (4136-91-8) + sodium dibenzyldithiocarbamate (55310-46-8)

Guidance literature:

With sodium nitrate; potassium hexacyanoferrate(III); In water; acetone; at 25 ℃; Equilibrium constant; μ 0.2 mol/l;

Reference yield:

sodium N,N'-diisopropyldithiocarbamate (4092-82-4) + C12H24N2S4 → tetraisopropylothiuram disulphide (4136-91-8) + sodium N,N-diethyldithiocarbamate (148-18-5)

Guidance literature:

With sodium nitrate; potassium hexacyanoferrate(III); In water; acetone; at 25 ℃; Equilibrium constant; μ 0.2 mol/l;

Reference yield:

sodium N,N'-diisopropyldithiocarbamate (4092-82-4) + C12H22N2S4 → tetraisopropylothiuram disulphide (4136-91-8) + sodium pyrrolidine-N-carbodithioate (872-71-9)

Guidance literature:

With sodium nitrate; potassium hexacyanoferrate(III); In water; acetone; at 25 ℃; Equilibrium constant; μ 0.2 mol/l;

upstream raw materials:

sodium N,N'-diisopropyldithiocarbamate

Downstream raw materials:

tetraisopropylthiuram monosulfide

Diisopropyl-dithiocarbamic acid 4-bromo-phenyl ester

Diisopropyl-dithiocarbamic acid 10-bromo-anthracen-9-yl ester

sodium N,N'-diisopropyldithiocarbamate

Refernces