Oxovanadium(IV) chloride

Base Information

• Chemical Name: Oxovanadium(IV) chloride
• CAS No.: 10213-09-9
• Molecular Formula: Cl2O V
• Molecular Weight: 137.847
• UNII: ET7948FWOY
• Wikidata: Q4332877
• Mol file: 10213-09-9.mol

Synonyms:OXOVANADIUM(IV) CHLORIDE;VANADYL DICHLORIDE [MI];VANADIUM CHLORIDE (VOCL2);Q4332877

Chemical Property of Oxovanadium(IV) chloride

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 17.07000
• Density: g/cm³
• LogP: 1.26020
• Water Solubility.: slowly decomposed in water; soluble absolute alcohol, glacial acetic acid [MER06]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 136.876578
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Strong irritant to tissue.
• Hazard Codes: Strong irritant to tissue.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [O-2].[Cl-].[Cl-].[V+4]
• Uses: Vanadium Dichloride Oxide has been used as mordant in printing fabrics.

Technology Process of Oxovanadium(IV) chloride

There total 6 articles about Oxovanadium(IV) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vanadia + chlorine (7782-50-5) → vanadyl chloride (10213-09-9) + vanadium(V) oxychloride (7727-18-6)

Guidance literature:

In neat (no solvent); byproducts: VCl3, O2; 600-1000°C;

DOI:10.1002/zaac.19966221006

Reference yield:

oxovanadium(IV) sulfate + barium(II) chloride dihydrate (10361-37-2) → vanadyl chloride (10213-09-9)

Guidance literature:

In ethanol; at 25 ℃; for 1h;

DOI:10.1016/j.ejmech.2014.07.098

Reference yield:

(C5H5)2V(2+) Chlorid → vanadyl chloride (10213-09-9)

Guidance literature:

With oxygen; In not given;

upstream raw materials:

vanadium(V) oxychloride

vanadyl-p-toluene sulfinate

chlorine

barium(II) chloride dihydrate

Downstream raw materials:

vanadium(V) oxychloride

vanadiumtetrachloride

vanadium oxychloride

VO(SALAHE)

Refernces

• 1、 Sausa, R. C.,Ronn, A. M.. "Pulsed CO2 laser induced chemistry of vanadium oxytrichloride (VOCl3)". . p. 1716 - 1724. Retrieved 1984.
• 2、 Balaji, Babu,Balakrishnan, Babita,Perumalla, Sravanakumar,Karande, Anjali A.,Chakravarty, Akhil R.. "Photoactivated cytotoxicity of ferrocenyl-terpyridine oxovanadium(IV) complexes of curcuminoids". . p. 458 - 467. Retrieved 2014/11/08.