Cyclopropanecarbonyl fluoride

Base Information

• Chemical Name: Cyclopropanecarbonyl fluoride
• CAS No.: 694-02-0
• Molecular Formula: C4H5FO
• Molecular Weight: 88.0815
• DSSTox Substance ID: DTXSID70504020
• Nikkaji Number: J151.087H
• Wikidata: Q82358216
• Mol file: 694-02-0.mol

Synonyms:Cyclopropanecarbonyl fluoride;694-02-0;cyclopropylcarbonyl fluoride;DTXSID70504020

Chemical Property of Cyclopropanecarbonyl fluoride

Chemical Property:

• PSA: 17.07000
• LogP: 0.89250
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 88.032442941
• Heavy Atom Count: 6
• Complexity: 75.6

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC1C(=O)F

Technology Process of Cyclopropanecarbonyl fluoride

There total 6 articles about Cyclopropanecarbonyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

cyclopropanecarboxylic acid chloride (4023-34-1) → cyclopropane carboxylic acid fluoroanhydride (694-02-0)

Guidance literature:

With hydrogen fluoride; at -78 - 5 ℃;

DOI:10.1016/S0022-1139(03)00174-X

Reference yield: 45.0%

cyclopropanecarboxylic acid (1759-53-1) → cyclopropane carboxylic acid fluoroanhydride (694-02-0)

Guidance literature:

With diethylamino-sulfur trifluoride; In dichloromethane;

DOI:10.1021/jo9903151

Reference yield:

Cyclopropanecarboxaldehyde (1489-69-6) → cyclopropane carboxylic acid fluoroanhydride (694-02-0)

Guidance literature:

With sodium decatungstate; N-fluorobis(benzenesulfon)imide; In acetonitrile; for 3h; UV-irradiation;

DOI:10.1039/c8cc06375c

upstream raw materials:

4-Chlorobutanoyl chloride

cyclopropanecarboxylic acid

cyclopropanecarboxylic acid chloride

Cyclopropanecarboxaldehyde

Downstream raw materials:

Fluormethyl-cyclopropyl-keton

Hexafluoroethane

perfluorobutyryl fluoride

Octafluorocyclobutane

Refernces

• 1、 Volltrauer,Schwendeman. "". . p. 268. Retrieved 1971.
• 2、 Hoerrner, Megan E.,Wang, Jiang,Watson, Mary P.,Weix, Daniel J.. "Nickel-Catalyzed Synthesis of Dialkyl Ketones from the Coupling of N-Alkyl Pyridinium Salts with Activated Carboxylic Acids". supporting information. p. 13484 - 13489. Retrieved 2020/06/10.
• 3、 Ignat'ev, Nikolai V.,Welz-Biermann, Urs,Heider, Udo,Kucheryna, Andriy,von Ahsen, Stefan,Habel, Wolfgang,Sartori, Peter,Willner, Helge. "Carbon-chain isomerization during the electrochemical fluorination in anhydrous hydrogen fluoride - A mechanistic study". . p. 21 - 37. Retrieved 2007/10/03.