Hexadec-5-ene

Base Information

• Chemical Name: Hexadec-5-ene
• CAS No.: 69820-25-3
• Molecular Formula: C16H32
• Molecular Weight: 224.43
• DSSTox Substance ID: DTXSID50300906
• Mol file: 69820-25-3.mol

Synonyms:hexadec-5-ene;DTXSID50300906

Chemical Property of Hexadec-5-ene

Chemical Property:

• XLogP3: 7.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 12
• Exact Mass: 224.250401021
• Heavy Atom Count: 16
• Complexity: 135

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCC=CCCCC

Technology Process of Hexadec-5-ene

There total 2 articles about Hexadec-5-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

Decyl-oxiran (2855-19-8) + butyl magnesium bromide (693-04-9) → 11-Hexadecanol (591-73-1) + (E)-5-hexadecene (69820-26-4) + (Z)-hexadec-5-ene (69820-25-3) + dodec-2-en-1-ol (22104-81-0)

Guidance literature:

With 2,2,6,6-tetramethylpiperidinyl-lithium; In diethyl ether; hexane; at 0 - 20 ℃; for 3h; Further Variations:; Solvents; Product distribution;

DOI:10.1021/jo070291v

Reference yield: 8.0%

Decyl-oxiran (2855-19-8) + n-butyllithium (109-72-8,29786-93-4) → Dodecanal (112-54-9) + (E)-5-hexadecene (69820-26-4) + (Z)-hexadec-5-ene (69820-25-3)

Guidance literature:

With 2,2,6,6-tetramethylpiperidinyl-lithium; In diethyl ether; hexane; at 0 - 20 ℃; for 2h; Further Variations:; Solvents; Reagents; Product distribution;

DOI:10.1021/jo070291v

Reference yield: 66.8%

(Z)-hexadec-5-ene (69820-25-3) → (Z)-11-hexadecen-1-ol (56683-54-6) + Δ5-hexadecenol (106463-48-3)

Guidance literature:

With CYP₅₂A₁₃ hydroxylase enzyme; oxygen; In water; at 30 ℃; Reagent/catalyst;

upstream raw materials:

Decyl-oxiran

butyl magnesium bromide

n-butyllithium

Downstream raw materials:

(Z)-11-hexadecen-1-ol

(Z)-11-hexadecenal

Δ5-hexadecenol

Refernces