1-Methoxyundecane

Base Information

• Chemical Name: 1-Methoxyundecane
• CAS No.: 7289-53-4
• Molecular Formula: C₁₂H₂₆O
• Molecular Weight: 186.338
• DSSTox Substance ID: DTXSID00337363
• Wikidata: Q82105154
• Mol file: 7289-53-4.mol

Synonyms:1-Methoxyundecane;7289-53-4;Methyl undecyl ether;1-Methoxyundecane #;SCHEMBL201220;DTXSID00337363

Chemical Property of 1-Methoxyundecane

Chemical Property:

• Melting Point: -43°C (estimate)
• Refractive Index: 1.4139 (estimate)
• Boiling Point: 220.85°C (estimate)
• PSA: 9.23000
• Density: 0.7995 (estimate)
• LogP: 4.16360
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 186.198365449
• Heavy Atom Count: 13
• Complexity: 81.2

Purity/Quality:

97% ^*data from raw suppliers

1-METHOXY-UNDECANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCOC

Technology Process of 1-Methoxyundecane

There total 4 articles about 1-Methoxyundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

methyl 10-undecenyl ether (7289-47-6) → 1-methoxyundecane (7289-53-4)

Guidance literature:

With iron(III) chloride; lithium aluminium tetrahydride; hydrogen; In tetrahydrofuran; at 18 ℃; for 3h; under 750.075 Torr; Inert atmosphere; Sealed tube;

DOI:10.1039/c4gc02368d

Reference yield:

1-methoxy-11-(toluene-4-sulfonyloxy)-undecane (94435-66-2) → 1-methoxyundecane (7289-53-4)

Guidance literature:

Multi-step reaction with 2 steps

1: NaI / acetone

2: Mg

With magnesium; sodium iodide; In acetone;

DOI:10.1039/P19760000465

Reference yield:

10-Undecen-1-ol (112-43-6) → 1-methoxyundecane (7289-53-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium hydride / paraffin oil; tetrahydrofuran / 2 h / 20 °C

1.2: 3 h / Reflux

2.1: hydrogen; iron(III) chloride; lithium aluminium tetrahydride / tetrahydrofuran / 3 h / 18 °C / 750.08 Torr / Inert atmosphere; Sealed tube

With iron(III) chloride; lithium aluminium tetrahydride; hydrogen; sodium hydride; In tetrahydrofuran; paraffin oil;

DOI:10.1039/c4gc02368d

upstream raw materials:

1-iodo-11-methoxy-undecane

1-methoxy-11-(toluene-4-sulfonyloxy)-undecane

methyl 10-undecenyl ether

10-Undecen-1-ol

Refernces

• 1、 Acheson,Harvey. "Synthesis of some 9-aminoacridines with bulky substituents.". . p. 465 - 470. Retrieved 2007/10/04.