CID 14966555

Base Information

• Chemical Name: CID 14966555
• CAS No.: 7366-24-7
• Molecular Formula: C6H6Cl2Ge
• Molecular Weight: 221.61
• DSSTox Substance ID: DTXSID60566192
• Nikkaji Number: J1.623.513J
• Wikidata: Q82451682
• Mol file: 7366-24-7.mol

Synonyms:

Chemical Property of CID 14966555

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 221.9058333
• Heavy Atom Count: 9
• Complexity: 79.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[GeH](Cl)Cl

Technology Process of CID 14966555

There total 5 articles about CID 14966555 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

phenylgermane (2875-92-5) + copper dichloride → phenyldichlorogermane (7366-24-7)

Guidance literature:

copper(l) iodide; In toluene; hydrogermane mixed with 4 equiv. of CuCl2 and CuI in toluene under reflux for 9 days; solvent evapd., distilled under reduced pressure;

DOI:10.1246/cl.2001.886

Reference yield: 50.0%

((C6H5)Cl2Ge)2Hg (68261-59-6) + isopropyl alcohol (67-63-0,8013-70-5) → (C6H5)Cl2GeOC3H7 (40841-19-8) + phenyldichlorogermane (7366-24-7)

Guidance literature:

In benzene-d6; byproducts: Hg; stirred until complet dissolution of suspn.; detected by NMR spectra;

DOI:10.1016/S0022-328X(00)85661-2

Reference yield: 40.0%

tri-n-butyl-tin hydride (688-73-3) + trichlorophenylgermane (1074-29-9) → tributyltin chloride (1461-22-9) + phenylgermane (2875-92-5) + phenylgermanium chloride (7366-22-5) + phenyldichlorogermane (7366-24-7)

Guidance literature:

In neat (no solvent); equimolar mixt. of reagents allowing to stand for 5 h at 20°C; analyzed by gas chromy. and NMR spectroscopy;

DOI:10.1016/S0022-328X(00)87640-8

upstream raw materials:

tetraphenyltin(IV)

germanium hydride trichloride

phenylgermane

tri-n-butyl-tin hydride

Downstream raw materials:

diphenylgermane

1,1,2,2-tetraphenyl 1,2-digermane

phenyldiethylgermane

1-Chlor-3,4-dimethyl-1-phenyl-1-germano-cyclopent-3-en

Refernces

• 1、 Castel, A.,Riviere, P.,Satge, J.. "ASSISTANCE NUCLEOPHILE DANS DES REACTIONS DE REDUCTION D'ORGANOHALOGENO- ET HALOGENO-GERMANES PAR DES REDUCTEURS DOUX R3M(IVB)-H ET RCHO: GERMYLANIONS, DERIVES FONCTIONNELS DU GERMANIUM". . p. 137 - 146. Retrieved 2007/10/02.