1,3-Cyclohexadiene, 1-nitro-

Base Information

• Chemical Name: 1,3-Cyclohexadiene, 1-nitro-
• CAS No.: 76356-92-8
• Molecular Formula: C6H7NO2
• Molecular Weight: 125.127
• Mol file: 76356-92-8.mol

Synonyms:

Chemical Property of 1,3-Cyclohexadiene, 1-nitro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-Cyclohexadiene, 1-nitro-

There total 2 articles about 1,3-Cyclohexadiene, 1-nitro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclohexa-1,3-diene (1165952-91-9) → 1-nitrocyclohexa-1,3-diene (76356-92-8)

Guidance literature:

With tetrafluoroboric acid; ammonium nitrate; potassium acetate; trifluoroacetic anhydride; Yield given. Multistep reaction; 1.) dichloromethane, 35 gradC 2.) ether, 20 gradC, 15 h.;

DOI:10.1016/S0040-4039(00)84124-6

Reference yield:

cyclohexa-1,3-diene (1165952-91-9) + trifluoroacetic anhydride (407-25-0) → 1-nitrocyclohexa-1,3-diene (76356-92-8)

Guidance literature:

With tetrafluoroboric acid; ammonium nitrate; potassium acetate; Yield given. Multistep reaction; 1.) dichloromethane, water, 35 deg C; 2.) ether, r.t., 18 h;

Reference yield: 82.0%

1-nitrocyclohexa-1,3-diene (76356-92-8) → 1-nitrocyclohexene (2562-37-0)

Guidance literature:

With <(Bu^t2PH)PdPBu^t2>2 pretreated with O2; hydrogen; In tetrahydrofuran; for 1h; Ambient temperature;

DOI:10.1016/00404-0399(50)11207-

upstream raw materials:

cyclohexa-1,3-diene

trifluoroacetic anhydride

Downstream raw materials:

1-nitrocyclohexene

C,N-diphenylnitrone

Refernces

• 1、 Bloom, A. Jon,Mellor, John M.. "SYNTHESIS OF 1-NITRO-1,3-DIENES VIA NITROTRIFLUOROACETOXYLATION OF 1,3-DIENES". . p. 873 - 876. Retrieved 2007/10/02.