1-Propanone, 1-(4-methoxyphenyl)-3-phenyl-3-thioxo-

Base Information

• Chemical Name: 1-Propanone, 1-(4-methoxyphenyl)-3-phenyl-3-thioxo-
• CAS No.: 76525-84-3
• Molecular Formula: C16H14O2S
• Molecular Weight: 270.352
• Mol file: 76525-84-3.mol

Synonyms:

Chemical Property of 1-Propanone, 1-(4-methoxyphenyl)-3-phenyl-3-thioxo-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Propanone, 1-(4-methoxyphenyl)-3-phenyl-3-thioxo-

There total 1 articles about 1-Propanone, 1-(4-methoxyphenyl)-3-phenyl-3-thioxo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.1%

Thiobenzoic acid O-ethyl ester (936-61-8) + 1-(4-methoxyphenyl)ethanone (100-06-1) → para-(methoxy)benzoyl(thiobenzoyl)methane (76525-84-3)

Guidance literature:

With sodium hydride; In tetrahydrofuran; at 60 ℃; for 18h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3dt52544a

Reference yield:

bismuth(III) chloride (7787-60-2) + para-(methoxy)benzoyl(thiobenzoyl)methane (76525-84-3) → tris(para-(methoxy)benzoyl-thiobenzoyl-methanato-O,S) bismuth(III)

Guidance literature:

With sodium acetate; In methanol; to a stirred soln. of BiCl3 a stoich. amt. of benzoyl-compd. in methanol and NaOAc are added, mixt. is stirred for 3-4 h (N2); filtered off, solvent is removed, crystn. from CH2Cl2/MeOH, elem. anal.;

DOI:10.1016/S0277-5387(00)86932-6

Reference yield:

copper diacetate (142-71-2) + para-(methoxy)benzoyl(thiobenzoyl)methane (76525-84-3) → Cu(C6H5CSCHCOC6H4OCH3-p)2

Guidance literature:

In methanol; water; byproducts: CH3COOH; metal acetate was mixed in aq. MeOH with aq. soln. of ligand in 1:2 molar ratio; filtered, washed with water, crystd. from dry methanol or acetonitrile,elem. anal.;

upstream raw materials:

Thiobenzoic acid O-ethyl ester

1-(4-methoxyphenyl)ethanone

Refernces

• 1、 Saini, S. K.,Gupta, V. D.,Mehrotra, R. C.. "Fe(III), Co(II), Cu(II) and Ni(II) Derivatives of Some New Monothio-β-Diketones". . p. 1424 - 1426. Retrieved 2007/10/02.