Chlorodimethylvinylsilane

Base Information Edit

Chemical Name:Chlorodimethylvinylsilane
CAS No.:1719-58-0
Molecular Formula:C4H9ClSi
Molecular Weight:120.654
Hs Code.:29319090
European Community (EC) Number:217-007-1
UNII:XJA6N5221T
DSSTox Substance ID:DTXSID5042378
Nikkaji Number:J203.112D
Wikidata:Q27293867
ChEMBL ID:CHEMBL3561435
Mol file:1719-58-0.mol

Synonyms:Chlorodimethylvinylsilane;1719-58-0;Dimethylvinylchlorosilane;Vinyldimethylchlorosilane;Chloro(dimethyl)vinylsilane;Silane, chloroethenyldimethyl-;chloro-ethenyl-dimethylsilane;Chlorodimethyl(vinyl)silane;vinyldimethylsilyl chloride;chloro(ethenyl)dimethylsilane;UNII-XJA6N5221T;XJA6N5221T;DTXSID5042378;EINECS 217-007-1;MFCD00018090;AI3-25204;EC 217-007-1;Vinylchlorodimethylsilane;CV-4720;dimethylchlorovinylsilane;dimethylvinylsilyl chloride;dimethyl vinyl chlorosilane;C4-H9-Cl-Si;SCHEMBL59866;Stannane, chloroethenyldimethyl-;CHEMBL3561435;DTXCID3022378;Chloro(dimethyl)vinylsilane, 97%;Tox21_303724;AKOS015916090;FS-3793;s21675;NCGC00357036-01;BP-21427;CAS-1719-58-0;FT-0623658;EN300-225080;J-010784;Q-200830;Q27293867

Suppliers and Price of Chlorodimethylvinylsilane

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Chlorodimethylvinylsilane
1mL
$ 45.00

TRC
Chlorodimethylvinylsilane
2mL
$ 60.00

TCI Chemical
Chlorodimethylvinylsilane >97.0%(GC)
25mL
$ 50.00

TCI Chemical
Chlorodimethylvinylsilane >97.0%(GC)
100mL
$ 131.00

Sigma-Aldrich
Chloro(dimethyl)vinylsilane 97%
100ml
$ 176.00

Sigma-Aldrich
Chloro(dimethyl)vinylsilane 97%
25ml
$ 66.10

Chem-Impex
Chlorodimethylvinylsilane,97%(GC) 97%(GC)
25ML
$ 45.92

Chem-Impex
Chlorodimethylvinylsilane,≥97%(GC)Hazmat ≥97%(GC)
100ML
$ 137.45

Biosynth Carbosynth
Chlorodimethylvinylsilane
250 g
$ 342.50

Biosynth Carbosynth
Chlorodimethylvinylsilane
500 g
$ 580.00

Total 94 raw suppliers

Chemical Property of Chlorodimethylvinylsilane Edit

Chemical Property:

Appearance/Colour:colorless clear liquid.
Vapor Pressure:95hPa at 20℃
Refractive Index:n20/D 1.414(lit.)
Boiling Point:82-83 °C(lit.)
Flash Point:-4 ºC
PSA：0.00000
Density:0.874
LogP:2.15550
Storage Temp.:Flammables area
Sensitive.:Moisture Sensitive
Solubility.:most aprotic organic solvents, but CH2Cl2 is most commonly used; reacts with H2O and other protic solvents.
Water Solubility.:Reacts with water.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:120.0162045
Heavy Atom Count:6
Complexity:58.6

Purity/Quality:

99.9% ^*data from raw suppliers

Chlorodimethylvinylsilane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,C
Statements: 11-14-34
Safety Statements: 16-26-33-36/37/39-45-25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Toxic Gases & Vapors -> Chlorosilanes
Canonical SMILES:C[Si](C)(C=C)Cl
Physical properties bp 82–83°C; d 0.874 gmL?1 at 25°C.
Uses Chlorodimethylvinylsilane is used to prepare silicon-containing polymers, silaheterocycles and new chelating ligands. Metallacycloalkanones have been prepared by the cyclic hydroboration of dialkenyl silanes. In order to obtain one such dialkenyl silane, chlorodimethylvinylsilanewas allylated with allyl magnesium bromide (eq 4).The dialkenyl silane was then hydroborated sequentially with thexylborane, followed by treatment with potassium cyanide, trifluoroacetic anhydride, and finally hydrogen peroxide in sodium hydroxide to produce the silacycloheptanone (eq 4).Cyclic silylketones were then further reacted to form acyclic compounds with chiral centers that are difficult to introduce without the use of the silicon tether.

Technology Process of Chlorodimethylvinylsilane

There total 21 articles about Chlorodimethylvinylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.7%

: 5356-83-2
ethoxydimethylvinylsilane

: 79-04-9
chloroacetyl chloride

: 1719-58-0
Chlorodimethylvinylsilane

Guidance literature:: With sodium hydrogencarbonate; sodium carbonate; at 35 ℃; for 4h; Reagent/catalyst; Temperature; Molecular sieve; Inert atmosphere;