Iodine, m-oxodiphenylbis(1,1,1-trifluoromethanesulfonato-kO)di-

Base Information

• Chemical Name: Iodine, m-oxodiphenylbis(1,1,1-trifluoromethanesulfonato-kO)di-
• CAS No.: 88016-29-9
• Molecular Formula: C14H10 F6 I2 O7 S2
• Molecular Weight: 722.161
• Mol file: 88016-29-9.mol

Synonyms:Iodine,m-oxodiphenylbis(trifluoromethanesulfonato-O)di-(9CI); Methanesulfonic acid, trifluoro-, iodine complex; NSC 644326; Reagents,Zefirov's; Zefirov's reagent

Chemical Property of Iodine, m-oxodiphenylbis(1,1,1-trifluoromethanesulfonato-kO)di-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Iodine, m-oxodiphenylbis(1,1,1-trifluoromethanesulfonato-kO)di-

There total 4 articles about Iodine, m-oxodiphenylbis(1,1,1-trifluoromethanesulfonato-kO)di- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

trifluoromethylsulfonic anhydride (358-23-6) + iodosylbenzene (536-80-1) → μ-oxobis[(trifluoromethanesulfonato)(phenyl)iodine] (88016-29-9)

Guidance literature:

In dichloromethane; for 0.416667h; Ambient temperature;

DOI:10.1021/jo00392a028

Reference yield: 73.0%

trifluorormethanesulfonic acid (1493-13-6) + [bis(acetoxy)iodo]benzene (3240-34-4) → μ-oxobis[(trifluoromethanesulfonato)(phenyl)iodine] (88016-29-9)

Guidance literature:

In chloroform;

DOI:10.1016/S0040-4039(00)84887-X

Reference yield:

[bis(acetoxy)iodo]benzene (3240-34-4) → μ-oxobis[(trifluoromethanesulfonato)(phenyl)iodine] (88016-29-9)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydroxide / water / 2 h / 20 °C

2: ethylenediamine / 0.67 h / Inert atmosphere

With sodium hydroxide; In water; ethylenediamine;

DOI:10.1002/ejoc.201300092

upstream raw materials:

trifluorormethanesulfonic acid

[bis(acetoxy)iodo]benzene

trifluoromethylsulfonic anhydride

iodosylbenzene

Downstream raw materials:

ethynylphenyl-iodonium-1,1,1-trifluoromethanesulfonate

bis(tri-n-butyltin)oxide

t-butylallene

Hexamethyldisiloxane

Refernces

• 1、 Dixon, Luke I.,Carroll, Michael A.,Gregson, Thomas J.,Ellames, George J.,Harrington, Ross W.,Clegg, William. "Synthesis and reactivity of aryl(alkynyl)iodonium salts". supporting information. p. 2334 - 2345. Retrieved 2013/05/21.
• 2、 Kitamura,Lee,Taniguchi,Fujiwara,Matsumoto,Sano. "A new route to chiral diaryldiacetylenic liquid crystals. Preparation of iodonium salts bearing chiral alkynyl ligands and utility for chiral alkynyl transfer agents". . p. 619 - 620. Retrieved 2007/10/03.