2-Methylbenzamide

Base Information Edit

Chemical Name:2-Methylbenzamide
CAS No.:527-85-5
Molecular Formula:C8H9NO
Molecular Weight:135.166
Hs Code.:2924299090
European Community (EC) Number:208-427-6
NSC Number:2169
UNII:13WGF92B0H
DSSTox Substance ID:DTXSID6025569
Nikkaji Number:J6.672I
Wikidata:Q27251545
ChEMBL ID:CHEMBL1489405
Mol file:527-85-5.mol

Synonyms:2-methylbenzamide

Suppliers and Price of 2-Methylbenzamide

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-Methylbenzamide
2.5g
$ 65.00

Sigma-Aldrich
2-Methylbenzamide 98%
25g
$ 54.30

Matrix Scientific
o-Toluamide
5g
$ 100.00

Matrix Scientific
o-Toluamide
25g
$ 406.00

Crysdot
2-Methylbenzamide 95+%
500g
$ 361.00

Chemenu
o-Toluamide 95%
500g
$ 341.00

Apolloscientific
o-Toluamide 98%
100g
$ 76.00

Apolloscientific
o-Toluamide 98%
25g
$ 29.00

American Custom Chemicals Corporation
2-METHYLBENZAMIDE 95.00%
10G
$ 1161.81

Alichem
2-Methylbenzamide
500g
$ 361.35

Total 24 raw suppliers

Chemical Property of 2-Methylbenzamide Edit

Chemical Property:

Appearance/Colour:white powder
Vapor Pressure:0.0174mmHg at 25°C
Melting Point:141-142 °C
Refractive Index:1.556
Boiling Point:254.3 °C at 760 mmHg
PKA:16.01±0.50(Predicted)
Flash Point:107.6 °C
PSA：43.09000
Density:1.086 g/cm³
LogP:1.79420
Storage Temp.:Sealed in dry,Room Temperature
Solubility.:alcohol: very soluble(lit.)
XLogP3:0.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:135.068413911
Heavy Atom Count:10
Complexity:133

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Methylbenzamide ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 22
Safety Statements: S22:Do not inhale dust.; S24/25:Avoid contact with skin and eyes.;

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Nitrogen Compounds -> Other Aromatics (Nitrogen)
Canonical SMILES:CC1=CC=CC=C1C(=O)N
Uses 2-Methylbenzamide (o-Toluamide) has been used in total synthesis of phenolic protoberberine alkaloid, cerasonine.

Technology Process of 2-Methylbenzamide

There total 57 articles about 2-Methylbenzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 529-19-1
2-Methylbenzonitrile

: 527-85-5
o-Methylbenzamid

Guidance literature:: With C₁₈H₅₇O₃P₆Ru₂⁽¹⁺⁾*C₆H₅O^(1-)*C₆H₆O; water; In 1,4-dioxane; for 24h; Time; Sealed tube; Inert atmosphere; Schlenk technique;
DOI:10.1016/j.poly.2016.04.006

Reference yield: 98.8%

: 20045-96-9
o-methylbenzoyl bromide

: 527-85-5
o-Methylbenzamid

Guidance literature:: o-methylbenzoyl bromide; With aluminum isopropoxide; dimethyl amine; In Cyclooctan; at 36 ℃; for 3h;

With potassium sulfate; zinc 2-ethylhexanoate; at 47 ℃; for 3.16667h; Temperature;