Diphenylhydroxyphosphoranethione

Base Information

• Chemical Name: Diphenylhydroxyphosphoranethione
• CAS No.: 14278-72-9
• Molecular Formula: C12H11 O P S
• Molecular Weight: 234.259
• Hs Code.: 2930909090
• Mol file: 14278-72-9.mol

Synonyms:Phosphinothioicacid, diphenyl- (6CI,8CI,9CI); Diphenylmonothiophosphinic acid;Diphenylphosphinothioic acid; Diphenylthiophosphinic acid; NSC 249212

Chemical Property of Diphenylhydroxyphosphoranethione

Chemical Property:

• Vapor Pressure: 1.28E-06mmHg at 25°C
• Boiling Point: 385.1°Cat760mmHg
• Flash Point: 186.7°C
• PSA: 62.13000
• Density: 1.28g/cm³
• LogP: 2.67480

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diphenylhydroxyphosphoranethione

There total 35 articles about Diphenylhydroxyphosphoranethione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

diphenylthiophosphinoyl chloride (1015-37-8) → [phenyl(sulfanyl)phosphoroso]benzene (14278-72-9) + diphenylphosphinodithioic acid (1015-38-9)

Guidance literature:

diphenylthiophosphinoyl chloride; With sodium hydrogen sulfide; In water; at 95 ℃; for 1h;

With hydrogenchloride; In water;

DOI:10.1071/CH20169

Reference yield: 40.0%

C30H25OPSSi (27387-68-4) → diphenylthiophosphinic acid (14278-72-9)

Guidance literature:

With water; In acetone; at 40 ℃; for 2h;

DOI:10.1016/S0040-4020(01)89077-3

Reference yield: 31.0%

Diphenylphosphine oxide (4559-70-0) → [phenyl(sulfanyl)phosphoroso]benzene (14278-72-9)

Guidance literature:

With n-butyllithium; sulfur; In tetrahydrofuran; hexane;

upstream raw materials:

Diphenylphosphine oxide

chloro-diphenylphosphine

diphenylthiophosphinoyl chloride

benzene

Downstream raw materials:

Diphenylphosphinic chloride

Diphenyl-phosphinothioic acid S-(2-oxo-propyl) ester

S-(sec-butyl) diphenylphosphinothioate

6-(diphenylphosphinylthio)-1,2-O-isopropylidene-α-D-glucofuranose

Refernces

• 1、 Harger, Martin J. P.. "N-(diphenylphosphinothioyl)hydroxylamine: Preparation, characterisation and base-induced transposition of sulfur and oxygen atoms in its O-benzoyl derivative". . p. 3205 - 3209. Retrieved 2007/10/03.
• 2、 Odinets,Artyushin,Kalyanova,Petrovskii,Lysenko,Antipin,Struchkov,Mastryukova,Kabachnik. "Acylation of Phosphorus-Substituted CH Acids under the Conditions of Phase-transfer Catalysis III. Acylation of Thiophosphinoylacetonitriles". . p. 43 - 53. Retrieved 2007/10/03.