Silane, (1-cyclohepten-1-yloxy)tris(1-methylethyl)-

Base Information

• Chemical Name: Silane, (1-cyclohepten-1-yloxy)tris(1-methylethyl)-
• CAS No.: 80522-48-1
• Molecular Formula: C16H32OSi
• Molecular Weight: 268.515
• Mol file: 80522-48-1.mol

Synonyms:

Chemical Property of Silane, (1-cyclohepten-1-yloxy)tris(1-methylethyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Silane, (1-cyclohepten-1-yloxy)tris(1-methylethyl)-

There total 1 articles about Silane, (1-cyclohepten-1-yloxy)tris(1-methylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

triisopropylsilyl trifluoromethanesulfonate (80522-42-5) + cycloheptanone (502-42-1) → 1-(triisopropylsiloxy)cycloheptene (80522-48-1)

Guidance literature:

With triethylamine; In dichloromethane; for 0.166667h;

DOI:10.1021/ol050284y

Reference yield: 74.0%

1-(triisopropylsiloxy)cycloheptene (80522-48-1) → 2-Cyclohepten-1-one (1121-66-0)

Guidance literature:

With tert.-butylhydroperoxide; disodium hydrogenphosphate; oxygen; palladium dihydroxide; In dichloromethane; at 24 ℃; for 44h;

DOI:10.1021/ol050284y

Reference yield:

C32H40O5 (1379829-57-8) + 1-(triisopropylsiloxy)cycloheptene (80522-48-1) → C39H52O6

Guidance literature:

With copper(II) perchlorate hexahydrate; C₂₄H₃₆N₂O₅; In dichloromethane; at 30 ℃; for 19h; stereoselective reaction; Inert atmosphere; Molecular sieve;

DOI:10.1002/anie.201300032

upstream raw materials:

triisopropylsilyl trifluoromethanesulfonate

cycloheptanone

Downstream raw materials:

2-Cyclohepten-1-one

Refernces

• 1、 Corey, E. J.,Cho, Hidetsura,Ruecker, Christoph,Hua, Duy H.. "STUDIES WITH TRIALKYLSILYLTRIFLATES: NEW SYNTHESES AND APPLICATIONS". . p. 3455 - 3458. Retrieved 2007/10/02.