Tris[4-(trifluoromethyl)phenyl]arsane

Base Information

• Chemical Name: Tris[4-(trifluoromethyl)phenyl]arsane
• CAS No.: 809-14-3
• Molecular Formula: C21H12AsF9
• Molecular Weight: 510.234
• DSSTox Substance ID: DTXSID00546519
• Nikkaji Number: J1.104.784J
• Wikidata: Q82424380
• Mol file: 809-14-3.mol

Synonyms:Tris[4-(trifluoromethyl)phenyl]arsane;809-14-3;DTXSID00546519

Chemical Property of Tris[4-(trifluoromethyl)phenyl]arsane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 3
• Exact Mass: 510.001123
• Heavy Atom Count: 31
• Complexity: 478

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C(F)(F)F)[As](C2=CC=C(C=C2)C(F)(F)F)C3=CC=C(C=C3)C(F)(F)F

Technology Process of Tris[4-(trifluoromethyl)phenyl]arsane

There total 3 articles about Tris[4-(trifluoromethyl)phenyl]arsane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

(4-trifluoromethylphenyl)lithium (2786-01-8) → tris(4-(trifluoromethyl)phenyl)arsane (809-14-3)

Guidance literature:

With arsenic(III) bromide; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/acs.inorgchem.0c00598

Reference yield: 65.0%

p-trifluoromethylphenyl bromide (402-43-7) → tris(4-(trifluoromethyl)phenyl)arsane (809-14-3)

Guidance literature:

p-trifluoromethylphenyl bromide; With n-butyllithium; In diethyl ether; hexane; at 0 ℃; for 1h; Inert atmosphere;

With arsenic(III) bromide; In diethyl ether; hexane; at 0 - 20 ℃;

DOI:10.1039/d1dt02955j

Reference yield:

→ tris(4-(trifluoromethyl)phenyl)arsane (809-14-3)

Guidance literature:

4-Trifluormethyl-phenyl-magnesiumbromid, Arsentrichlorid, Ae.;

DOI:10.1139/v63-224

upstream raw materials:

p-trifluoromethylphenyl bromide

(4-trifluoromethylphenyl)lithium

Refernces

• 1、 Tanaka, Susumu,Konishi, Masafumi,Imoto, Hiroaki,Nakamura, Yuma,Ishida, Masatoshi,Furuta, Hiroyuki,Naka, Kensuke. "Fundamental Study on Arsenic(III) Halides (AsX3; X = Br, I) toward the Construction of C3-Symmetrical Monodentate Arsenic Ligands". supporting information. p. 9587 - 9593. Retrieved 2020/07/02.