2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane

Base Information

• Chemical Name: 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane
• CAS No.: 3388-04-3
• Deprecated CAS: 155684-30-3,52682-88-9,1203548-49-5,2104745-96-0,1203548-49-5
• Molecular Formula: C11H22O4Si
• Molecular Weight: 246.379
• Hs Code.: 29319090
• European Community (EC) Number: 222-217-1
• NSC Number: 139838
• UNII: SXJ79LS078
• DSSTox Substance ID: DTXSID1043910
• Nikkaji Number: J54.321G
• Wikidata: Q26841239
• Mol file: 3388-04-3.mol

Synonyms:(3,4-epoxycyclohexyl)ethyltrimethoxysilane;ECEMS

Chemical Property of 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane

Chemical Property:

• Vapor Pressure: 0.0167mmHg at 25°C
• Melting Point: <0 °C
• Refractive Index: n20/D 1.451(lit.)
• Boiling Point: 263.5 °C at 760 mmHg
• Flash Point: 89.7 °C
• PSA: 40.22000
• Density: 1.034 g/cm³
• LogP: 1.82210
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Water Solubility.: 1.4g/L at 20℃
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 246.12873571
• Heavy Atom Count: 16
• Complexity: 224

Purity/Quality:

99% ^*data from raw suppliers

2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 45-46-45/46
• Safety Statements: 53-23-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> Epoxides
• Canonical SMILES: CO[Si](CCC1CCC2C(C1)O2)(OC)OC
• Uses: Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane may be used as a precursor to form SiCOH film via sol-gel. The silane may be used to functionalize alumina nanoparticles towards the fabrication of polyamide 12/alumina nanocomposites. 4 Basalt fibers were functionalized with this silane and its consequent effect on the fabrication of basalt fiber–epoxidized vegetable oil matrix composite materials was analyzed.Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane can be used as a silane based coupling agent to functionalize a variety of substrates. It modifies the surface to improve the dispersion of nanoparticles. It can be used as an adhesion promoter by treating the precursor material with epoxy silanes. Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane was used as an adhesion promoter during the fabrication of:a photoacid generator activated by two photon excitation. nanoscale polymeric structures (width: 65 nm) using 520 nm femtosecond pulse excitation. Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane may be used as a precursor to form SiCOH film via sol-gel. The silane may be used to functionalize alumina nanoparticles towards the fabrication of polyamide 12/alumina nanocomposites. 4 Basalt fibers were functionalized with this silane and its consequent effect on the fabrication of basalt fiber–epoxidized vegetable oil matrix composite materials was analyzed.

Technology Process of 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane

There total 3 articles about 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.9%

→ trimethoxy[2-(7-oxabicyclo[4.1.0]-hept-3-yl)ethyl]silane (3388-04-3)

Guidance literature:

Reference yield: 90.0%

1,2-Epoxy-4-vinylcyclohexane (106-86-5) + γ-methacryloxypropyltrichlorosilane + trimethoxysilane (2487-90-3) → trimethoxy[2-(7-oxabicyclo[4.1.0]-hept-3-yl)ethyl]silane (3388-04-3)

Guidance literature:

chloroplatinic acid;

Reference yield: 74.0%

1,2-Epoxy-4-vinylcyclohexane (106-86-5) + trimethoxysilane (2487-90-3) → trimethoxy[2-(7-oxabicyclo[4.1.0]-hept-3-yl)ethyl]silane (3388-04-3)

Guidance literature:

With 2C₄H₉O^(1-)*Ni⁽²⁺⁾*(x)KCl; In tetrahydrofuran; at 20 ℃; for 12h; Glovebox; Inert atmosphere;

DOI:10.1002/anie.201606832

upstream raw materials:

1,2-Epoxy-4-vinylcyclohexane

trimethoxysilane

Refernces

• 1、 -. "PDO OR BMTZ LIGAND FOR SUPPORTED COORDINATED PT HYDROSILYLATION CATALYSTS". Paragraph 0034; 0128. . Retrieved 2021/03/13.
• 2、 -. "Noble metal supported on a base metal catalyst". . . Retrieved 2008/06/13.