DIMETHYL HEXADECANEDIOATE

Base Information

• Chemical Name: DIMETHYL HEXADECANEDIOATE
• CAS No.: 19102-90-0
• Molecular Formula: C18H34O4
• Molecular Weight: 314.466
• Hs Code.: 2917190090
• Mol file: 19102-90-0.mol

Synonyms:Hexadecanedioicacid, dimethyl ester (6CI,7CI,8CI,9CI);1,14-Tetradecanedicarboxylic aciddimethyl ester;Dimethyl hexadecanedioate;Dimethyl thapsate;

Chemical Property of DIMETHYL HEXADECANEDIOATE

Chemical Property:

• Melting Point: 53 °C
• Boiling Point: 351.3 °C at 760 mmHg
• Flash Point: 157.5 °C
• PSA: 52.60000
• Density: 0.945 g/cm³
• LogP: 4.79380

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dimethyl Hexadecanedioate >95.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIMETHYL HEXADECANEDIOATE

There total 21 articles about DIMETHYL HEXADECANEDIOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

azelaic monomethyl ester (2104-19-0) → methyl octanate (111-11-5) + oct-7-enoic acid methyl ester (15766-90-2) + dimethyl hexadecanedioate (19102-90-0)

Guidance literature:

With potassium hydroxide; In methanol; at 45 ℃; Yield given; electrolysis: anode: platinum foil; current source: galvanostat; current density 220 mA cm^-2; current consumption: 1.4 F mol^-1; cell voltage 20 V;

DOI:10.3891/acta.chem.scand.52-0672

Reference yield: 69.0%

methanol (67-56-1) + thapsic acid (505-54-4) → dimethyl hexadecanedioate (19102-90-0)

Guidance literature:

With hydrogenchloride; In water; at 20 ℃; for 4h;

DOI:10.1002/pola.27673

Reference yield: 63.0%

azelaic monomethyl ester (2104-19-0) → dimethyl hexadecanedioate (19102-90-0)

Guidance literature:

With sodium; In pyridine; methanol; at 20 ℃; electrolysis, Pt-anode, other anodes;

DOI:10.1246/cl.1991.1085

upstream raw materials:

azelaic monomethyl ester

methanol

1-Chlorohexadecan

hexadecyl methyl ether

Downstream raw materials:

cyclopentadecanone

15-(methoxycarbonyl)pentadecanoic acid

1,16-hexadecanediol

3-methylcyclopentadecanone

Refernces

• 1、 Torron, Susana,Johansson, Mats. "Oxetane-terminated telechelic epoxy-functional polyesters as cationically polymerizable thermoset resins: Tuning the reactivity with structural design". . p. 2258 - 2266. Retrieved 2015.
• 2、 Corcoran, Jonathan,Rodriguez, Fernando,Rozas, Isabel,Meana, J. Javier,Callado, Luis F.. "On the search of new I2-IBS aliphatic ligands: Bis-guanidino carbonyl derivatives". . p. 6009 - 6012. Retrieved 2008/09/16.