Vinyl phosphine

Base Information

• Chemical Name: Vinyl phosphine
• CAS No.: 58436-39-8
• Molecular Formula: C2H5P
• Molecular Weight: 60.0349
• Hs Code.: 2901299090
• DSSTox Substance ID: DTXSID60207139
• Nikkaji Number: J264.207G
• Wikidata: Q83081032
• Mol file: 58436-39-8.mol

Synonyms:Vinyl phosphine;vinylphosphine;58436-39-8;DTXSID60207139

Chemical Property of Vinyl phosphine

Chemical Property:

• Vapor Pressure: 764mmHg at 25°C
• Boiling Point: 24.9°Cat760mmHg
• Flash Point: °C
• PSA: 13.59000
• Density: g/cm³
• LogP: 1.00500
• XLogP3: 0.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 60.012887157
• Heavy Atom Count: 3
• Complexity: 10.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CP

Technology Process of Vinyl phosphine

There total 10 articles about Vinyl phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

Diethyl vinylphosphonate (682-30-4) → ethenylphosphine (58436-39-8)

Guidance literature:

With dichloroalane; In various solvent(s); for 12h; Ambient temperature;

DOI:10.1016/0022-328X(89)80084-1

Reference yield: 70.0%

9,10-dihydro-9,10-ethanoanthracen-11-ylphosphine (109051-00-5) → ethenylphosphine (58436-39-8)

Guidance literature:

at 650 ℃; under 1E-06 Torr;

DOI:10.1039/c39860001428

Reference yield: 65.0%

dimethylvinylphosphonate (4645-32-3) → ethenylphosphine (58436-39-8)

Guidance literature:

With lithium aluminium tetrahydride; aluminium trichloride; hydroquinone; In various solvent(s); under 0.04 Torr; 1.) room temp., 2 h, 2.) 35-40 deg C, 30 min;

DOI:10.1039/DT9940000871

upstream raw materials:

dimethylvinylphosphonate

9,10-dihydro-9,10-ethanoanthracen-11-ylphosphonate

Diethyl vinylphosphonate

1,4-epoxy-1,4-diphenyl-1,2,3,4-tetrahydronaphtalen-2-yl-phosphine

Downstream raw materials:

benzylvinylphosphine

1-phosphapropene

Refernces

• 1、 Morise, Xavier,Green, Malcolm L. H.,McGowan, Patrick C.,Simpson, Stephen J.. "η-Cyclopentadienyltungsten Compounds with Vinyl- and Allyl-phosphine Ligands". . p. 871 - 878. Retrieved 1994.
• 2、 -. "NOVEL VINYL PHOSPHINES AND PHOTO-INITIATORS OBTAINABLE THEREFROM". Page/Page column 38. . Retrieved 2019/10/04.
• 3、 Mó, Otilia,Yá?ez, Manuel,Decouzon, Michèle,Gal, Jean-Fran?ois,Maria, Pierre-Charles,Guillemin, Jean-Claude. "Gas-phase basicity and acidity trends in α,β-unsaturated amines, phosphines, and arsines". . p. 4653 - 4663. Retrieved 2007/10/03.