Decanoyl peroxide

Base Information

• Chemical Name: Decanoyl peroxide
• CAS No.: 762-12-9
• Molecular Formula: C20H38 O4
• Molecular Weight: 342.519
• European Community (EC) Number: 212-092-1
• UN Number: 3114,3102
• UNII: 5YFN3ID35B
• DSSTox Substance ID: DTXSID0061084
• Nikkaji Number: J2.110E
• Wikidata: Q27263048
• Mol file: 762-12-9.mol

Synonyms:DECANOYL PEROXIDE;Peroxide, bis(1-oxodecyl);762-12-9;Bisdecanoyl peroxide;decanoic peroxyanhydride;UNII-5YFN3ID35B;5YFN3ID35B;EINECS 212-092-1;EC 212-092-1;didecanoyl peroxide;decanoyl decaneperoxoate;caproyl peroxide;DECANOX F;PERKADOX SE 10;SCHEMBL23375;DTXSID0061084;NA2120;UN2120;Q27263048

Chemical Property of Decanoyl peroxide

Chemical Property:

• Vapor Pressure: 4.98E-07mmHg at 25°C
• Melting Point: 40-41 °C
• Boiling Point: 413°C at 760 mmHg
• Flash Point: 174°C
• PSA: 52.60000
• Density: 0.936g/cm³
• LogP: 6.26920
• Water Solubility.: 121.6μg/L at 20.5℃
• XLogP3: 8.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 19
• Exact Mass: 342.27700969
• Heavy Atom Count: 24
• Complexity: 272
• Transport DOT Label: Organic Peroxide

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC

Technology Process of Decanoyl peroxide

There total 3 articles about Decanoyl peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

1-decanoic acid (334-48-5) → didecanoyl peroxide (762-12-9)

Guidance literature:

1-decanoic acid; With dmap; dihydrogen peroxide; In dichloromethane; at -15 ℃; for 0.25h;

With dicyclohexyl-carbodiimide; In dichloromethane; for 3h;

DOI:10.1021/acs.joc.9b02875

Reference yield:

n-decanoyl chloride (112-13-0) → didecanoyl peroxide (762-12-9)

Guidance literature:

With sodium hydroxide; water; dihydrogen peroxide;

Reference yield:

→ didecanoyl peroxide (762-12-9)

Guidance literature:

Caprinoylchlorid, H2O2, Py./Ae. (2h <-5grad);

upstream raw materials:

n-decanoyl chloride

1-decanoic acid

Downstream raw materials:

5-Methoxy-2-methyl-3-nonyl-[1,4]benzoquinone

Refernces