Lthium triazide

Base Information

• Chemical Name: Lthium triazide
• CAS No.: 19597-69-4
• Molecular Formula: LiN3
• Molecular Weight: 48.9611
• Hs Code.: 28500090
• Nikkaji Number: J43.857J
• Mol file: 19597-69-4.mol

Synonyms:Lthium triazide

Chemical Property of Lthium triazide

Chemical Property:

• Melting Point: decomposes at 115–298℃ [CRC10]
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 49.75000
• Density: g/cm³
• LogP: 0.21376
• Water Solubility.: g/100g H2O: 61.3 (0°C), 67.2 (20°C), 86.6 (60°C) [LAN05]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 49.02522545
• Heavy Atom Count: 4
• Complexity: 26.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

LithiumAzide(~20%inWater) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T+
• Statements: 26/27/28-32
• Safety Statements: 23-36/37/39-45-36/37-28

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Li+].[N-]=[N+]=[N-]

Technology Process of Lthium triazide

There total 11 articles about Lthium triazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

lithium sulfate + sodium azide → lithium azide (19597-69-4,157302-05-1)

Guidance literature:

lithium sulfate; sodium azide; In water; for 0.166667h;

In ethanol; for 0.166667h;

DOI:10.1039/c4ra08317b

Reference yield: 71.0%

sodium azide + lithium chloride → lithium azide (19597-69-4,157302-05-1)

Guidance literature:

In ethanol; byproducts: NaCl; anhydr. powdered LiCl dissolved in abs. EtOH, addition of a soln. of Na-azide in H2O;; purification EtOH and ether;;

Reference yield:

ammonium azide + lithium (7439-93-2) → lithium azide (19597-69-4,157302-05-1)

Guidance literature:

byproducts: NH3, H2;

upstream raw materials:

nitrogen

lithium

hydrogen azide

lithium hydroxide

Downstream raw materials:

cyanogen azide

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hexaazido cyclotriphosphazene

octachlorocyclotetraphosphazene

Refernces

• 1、 Conway, Louis P.,Delley, Richard J.,Neville, Jonathan,Freeman, Gemma R.,Maple, Hannah J.,Chan, Vincent,Hall, Alexander J.,Hodgson, David R. W.. "The aqueous N-phosphorylation and N-thiophosphorylation of aminonucleosides". . p. 38663 - 38671. Retrieved 2014/11/07.
• 2、 Yamasaki,Araki,Zakhidov,Mizobuchi,Yakushi,Yoshino. "A new metastable superconductor Li2Na1NyC60 prepared from azides". . p. 265 - 270. Retrieved 2008/10/09.