MONO-2-(METHACRYLOYLOXY)ETHYL SUCCINATE

Base Information

• Chemical Name: MONO-2-(METHACRYLOYLOXY)ETHYL SUCCINATE
• CAS No.: 20882-04-6
• Deprecated CAS: 104981-69-3,875903-68-7,942505-98-8,1158919-37-9,1632383-66-4,65233-26-3
• Molecular Formula: C10H14O6
• Molecular Weight: 230.218
• Hs Code.: 2918990090
• European Community (EC) Number: 244-096-4
• DSSTox Substance ID: DTXSID20864964
• Nikkaji Number: J192.366H
• Wikidata: Q81986404
• Mol file: 20882-04-6.mol

Synonyms:succinic acid mono(2-methacryloloxyethyl) ester;mono-2-(Methacryloyloxy)ethyl succinate;EINECS 244-096-4;4-[2-(methacryloyloxy)ethoxy]-4-oxobutanoic acid;2-methacryloyloxyethylsuccinic acid;mono-methacryloyloxyethylsuccinic acid;butanedioic acid mono 2-(methacryloyloxy)ethyl ester;succinic acid mono-2-methacryloyloxyethyl ester;I04-9459;

Chemical Property of MONO-2-(METHACRYLOYLOXY)ETHYL SUCCINATE

Chemical Property:

• Vapor Pressure: 3.42E-07mmHg at 25°C
• Refractive Index: n20/D 1.464(lit.)
• Boiling Point: 390.7°Cat760mmHg
• PKA: 4.35±0.17(Predicted)
• Flash Point: 151°C
• PSA: 89.90000
• Density: 1.211g/cm³
• LogP: 0.51370
• Storage Temp.: 2-8°C
• XLogP3: 0.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 9
• Exact Mass: 230.07903816
• Heavy Atom Count: 16
• Complexity: 294

Purity/Quality:

99.9% ^*data from raw suppliers

mono-2-(Methacryloyloxy)ethyl succinate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCCOC(=O)CCC(=O)O

Technology Process of MONO-2-(METHACRYLOYLOXY)ETHYL SUCCINATE

There total 3 articles about MONO-2-(METHACRYLOYLOXY)ETHYL SUCCINATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-methyl-2-propenoic acid 2-hydroxyethyl ester (868-77-9,141668-69-1,25736-86-1,82601-55-6,25249-16-5) + succinic acid anhydride (108-30-5) → 2-methacryloyloxyethyl hydrogen succinate (20882-04-6)

Guidance literature:

With 4-methoxy-phenol; at 90 ℃; for 18h;

DOI:10.1002/(SICI)1521-3765(19990301)5:3<937::AID-CHEM937>3.0.CO;2-0

Reference yield:

(2-nitro-1,4-phenylene)dimethanol (23222-97-1) + methacrylic acid 2-(3-chlorocarbonylpropionyloxy)ethyl ester (96297-73-3) → C18H19NO8 + 2-methacryloyloxyethyl hydrogen succinate (20882-04-6)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / tetrahydrofuran / 20 °C

2: tetrahydrofuran / 10 h / UV-irradiation

With triethylamine; In tetrahydrofuran;

DOI:10.1039/c0sm00638f

Reference yield:

bis(2-(methacryloyloxy)ethyl) O,O’-((2-nitro-1,4-phenylene)bis(methylene)) disuccinatE (1269794-13-9) → C18H19NO8 + 2-methacryloyloxyethyl hydrogen succinate (20882-04-6)

Guidance literature:

In tetrahydrofuran; for 10h; Kinetics; UV-irradiation;

DOI:10.1039/c0sm00638f

upstream raw materials:

2-methyl-2-propenoic acid 2-hydroxyethyl ester

succinic acid anhydride

(2-nitro-1,4-phenylene)dimethanol

methacrylic acid 2-(3-chlorocarbonylpropionyloxy)ethyl ester

Downstream raw materials:

bis(2-(methacryloyloxy)ethyl) O,O’-((2-nitro-1,4-phenylene)bis(methylene)) disuccinatE

Refernces

• 1、 -. "PHOTO-CLEAVABLE PRIMER COMPOSITIONS AND METHODS OF USE". Paragraph 0099. . Retrieved 2017/08/24.
• 2、 Van Esch, Jan,Schoonbeek, Franck,De Loos, Maaike,Kooijman, Huub,Spek, Anthony L.,Kellogg, Richard M.,Feringa, Ben L.. "Cyclic bis-urea compounds as gelators for organic solvents". . p. 937 - 950. Retrieved 2007/10/03.