beta-D-galactofuranose

Base Information

• Chemical Name: beta-D-galactofuranose
• CAS No.: 7045-51-4
• Molecular Formula: C₆H₁₂O₆
• Molecular Weight: 180.158
• UNII: TC2Q4G87B7
• Nikkaji Number: J748.253A
• Wikidata: Q27126749
• Metabolomics Workbench ID: 60654
• Mol file: 7045-51-4.mol

Synonyms:beta-D-galactofuranose;Galf;TC2Q4G87B7;7045-51-4;Galactofuranose, beta-D-;UNII-TC2Q4G87B7;CHEBI:59497;(2R,3R,4R,5S)-5-[(1R)-1,2-dihydroxyethyl]oxolane-2,3,4-triol;beta-galactofuranose;SCHEMBL363729;AVVWPBAENSWJCB-DGPNFKTASA-N;GALACTOFURANOSE, .BETA.-D-;Q27126749;WURCS=2.0/1,1,0/(a2112h-1b_1-4)/1/

Chemical Property of beta-D-galactofuranose

Chemical Property:

• XLogP3: -2.6
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 2
• Exact Mass: 180.06338810
• Heavy Atom Count: 12
• Complexity: 151

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C1C(C(C(O1)O)O)O)O)O
• Isomeric SMILES: C([C@H]([C@H]1[C@@H]([C@H]([C@@H](O1)O)O)O)O)O

Technology Process of beta-D-galactofuranose

There total 1 articles about beta-D-galactofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(4-nitro)phenyl β-D-galactofuranoside (100645-45-2) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + β-D-qalactofuranose (7045-51-4)

Guidance literature:

With α-L-arabinofuranosidase AbfD3; water; at 60 ℃; Enzyme kinetics;

DOI:10.1016/j.bmcl.2006.10.032

Reference yield:

β-D-qalactofuranose (7045-51-4) + 2-methyl-5-tert-butylthiophenol (7340-90-1) → (2-methyl-5-tert-butylphenyl) 1-thio-β-D-galactofuranoside (1269500-76-6)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.carres.2015.08.014

Reference yield:

β-D-qalactofuranose (7045-51-4) → C55H56O12 + C55H56O12

Guidance literature:

Multi-step reaction with 3 steps

1: boron trifluoride diethyl etherate / dichloromethane / 2 h / 20 °C / Inert atmosphere

2: sodium hydride / mineral oil; N,N-dimethyl-formamide

3: N-Bromosuccinimide; trifluorormethanesulfonic acid / dichloromethane / 0.5 h / 0 °C / Molecular sieve; Inert atmosphere

With N-Bromosuccinimide; trifluorormethanesulfonic acid; boron trifluoride diethyl etherate; sodium hydride; In dichloromethane; N,N-dimethyl-formamide; mineral oil;

DOI:10.1016/j.carres.2015.08.014

upstream raw materials:

(4-nitro)phenyl β-D-galactofuranoside

Downstream raw materials:

(2-methyl-5-tert-butylphenyl) 1-thio-β-D-galactofuranoside

Refernces