Lithium bis((trifluoromethyl)sulfonyl)azanide

Base Information

• Chemical Name: Lithium bis((trifluoromethyl)sulfonyl)azanide
• CAS No.: 90076-65-6
• Deprecated CAS: 149330-06-3,157306-34-8,230309-67-8,327155-75-9,716377-02-5,732284-91-2,848585-66-0,858642-85-0,876273-90-4,900160-17-0,1000693-70-8,1086269-49-9,1122573-46-9,1184304-91-3,1290058-32-0,1357997-90-0,1445874-17-8,1465133-90-7,1613165-06-2,1620207-60-4,1644364-49-7,1772606-15-1,1937276-37-3,2043073-41-0,2088571-19-9,2095311-25-2,2099044-97-8,2088060-53-9,2101914-80-9,2221058-91-7,2226338-84-5,2095698-07-8,2242726-01-6,2243227-82-7,2452229-63-7,2640832-88-6,2600796-04-9,1000693-70-8,1086269-49-9,1122573-46-9,1184304-91-3,1290058-32-0,1357997-90-0,157306-34-8,327155-75-9,716377-02-5,732284-91-2,848585-66-0,858642-85-0,876273-90-4,900160-17-0
• Molecular Formula: C2F6LiNO4S2
• Molecular Weight: 287.09
• Hs Code.: 29309090
• European Community (EC) Number: 415-300-0,618-438-1
• UNII: 9Y730392A5
• DSSTox Substance ID: DTXSID8044468
• Nikkaji Number: J635.481E
• Wikipedia: Lithium_bis(trifluoromethanesulfonyl)imide
• Wikidata: Q27273378
• Mol file: 90076-65-6.mol

Synonyms:90076-65-6;Lithium Bis(trifluoromethanesulfonyl)imide;Lithium bis((trifluoromethyl)sulfonyl)azanide;Bis(trifluoromethane)sulfonimide lithium salt;lithium bis(trifluoromethanesulphonyl)imide;Lithium bis((trifluoromethyl)sulfonyl)amide;Lithium Triflimide;LiTFSI;lithium bis(trifluoromethylsulfonyl)imide;lithium;bis(trifluoromethylsulfonyl)azanide;Lithium bis(trifluoromethanesulfonyl)amide;bistrifluoromethanesulfonimide lithium salt;Bis[(trifluoromethyl)sulfonyl]imide lithium salt;UNII-9Y730392A5;MFCD00210017;lithium bis(trifluoromethylsulfonyl)amide;9Y730392A5;Lithium bis[(trifluoromethane)sulphonyl]imide;Bis(trifluoromethanesulfonyl)imide Lithium Salt;EC 415-300-0;Methanesulfonamide, 1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)-, lithium salt (1:1);bistrifluoromethanesulfonimidate;Methanesulfonamide, 1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)-, lithium salt;Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-, lithium salt;Lithium bis[(trifluoromethyl)sulfonyl]azanide;Lithium Bis(trifluoromethylsulfonyl)azanide;Lithium TFSI;LiTFSl;Methanesulfonamide, 1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)-,lithium salt;Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-,lithium salt;Lithium triflimide+;Lithium bis(trifluoromethylsulphonyl)imide;SANKONOL MEK-50R;C2HF6NO4S2.Li;FLUORAD HQ-115;LiN(SO2CF3)2;LITHIUM BISTRIFLAMIDE;SCHEMBL88726;DTXSID8044468;C2-H-F6-N-O4-S2.Li;AKOS005063311;AKOS025310128;FS-3803;SB40653;Bis(trifluoromethane)sulfonimidelithiumsalt;lithium bis(trifluoromethylsulfonyl) amide;bis(trifluoromethane sulfonyl)imide lithium;lithium bis((trifiuoromethyl)sulfonyl)amide;lithium bis(trifluoromethane-sulfonyl)imide;lithium bis[(trifluoromethyl)sulfonyl]imide;J635.481E;B2542;FT-0627890;Bis(trifluoromethane)sulphonimide lithium salt,;P17513;A843440;Bistrifluoromethanesulfonimide lithium salt (LiTFSi);Lithium bis(trifluoromethanesulphonyl)imide (LiTFSI);Q-101273;LITHIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE(1-);LITHIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDATE(1-);Q27273378;F1905-7229;Lithium bis(trifluoromethylsulfonyl)imide, 80% in water;Bis(trifluoromethane)sulfonimide lithium salt, 99.95% trace metals basis;Bis(trifluoromethane)sulfonimide lithium salt, puriss., >=99.0% (19F-NMR);lithium salt;1,1,1-trifluoro-N-(trifluoromethylsulfonyl)methanesulfonamide;2043073-41-0

Chemical Property of Lithium bis((trifluoromethyl)sulfonyl)azanide

Chemical Property:

• Appearance/Colour: white hygroscopic powder
• Vapor Pressure: 0.54mmHg at 25°C
• Melting Point: 234-238 °C(lit.)
• Boiling Point: 190.5oC at 760 mmHg
• Flash Point: 69oC
• PSA: 88.28000
• Density: 1.334 g/cm³
• LogP: 2.61350
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Moisture Sensitive
• Solubility.: H2O: 10 mg/mL, clear, colorless
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 2
• Exact Mass: 286.93329724
• Heavy Atom Count: 16
• Complexity: 379

Purity/Quality:

99.5%min , ^*data from raw suppliers

Lithium bis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,C
• Hazard Codes: T,C
• Statements: 24/25-34-52/53-48/22
• Safety Statements: 22-26-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Compounds, Metal Salts
• Canonical SMILES: [Li+].C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
• Description: Lithium bis(trifluoromethylsulphonyl)imide (LiTFSI) is normally used as a p-dopant?to enhance the conductivity and hole mobility of the?Spiro-OMeTAD for perovskite solar cells. It is believed that The function of LiTFSI in PSCs is?similar to that in solid-state dye-sensitised solar cells [2].
• Uses: It finds application in the preparation of rare-earth Lewis acid catalysts. Lithium bis(trifluoromethylsulfonyl)imide is used in the preparation of chiral imidazolium salt through an anion metathesis of the corresponding triflate organic electrolyte-based lithium batteries. It finds application in the preparation of rare-earth Lewis acid catalysts. It is also useful in primary and secondary lithium cells using organic liquid electrolytes and polymer batteries.

Technology Process of Lithium bis((trifluoromethyl)sulfonyl)azanide

There total 13 articles about Lithium bis((trifluoromethyl)sulfonyl)azanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

triethylammonium bis(trifluoromethanesulfonyl)imide (192998-66-6) → bis(trifluoromethane)sulfonimide lithium (90076-65-6)

Guidance literature:

With Li pretreated ion exchange resin; In water; at 30 ℃; for 6h;

Reference yield: 98.8%

trifluoromethane sulfonyl chloride (421-83-0) + trifluoromethylsulfonimide lithium salt → bis(trifluoromethane)sulfonimide lithium (90076-65-6)

Guidance literature:

With lithium carbonate; In acetonitrile; Reagent/catalyst;

Reference yield: 98.0%

bis(trifluoromethanesulfonyl)amide (82113-65-3) → bis(trifluoromethane)sulfonimide lithium (90076-65-6)

Guidance literature:

With lithium hydroxide;

DOI:10.1016/j.jfluchem.2003.07.003

upstream raw materials:

Trifluoromethanesulfonyl fluoride

bis(trifluoromethanesulfonyl)amide

triethylammonium bis(trifluoromethanesulfonyl)imide

trifluoromethane sulfonyl chloride

Downstream raw materials:

1-butyl-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide

1-butyl-3-methylimidazolium trifluoromethanesulfonimide

1-methyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

N,N,N-trimethyl-N-(2-hydroxyethyl)ammonium bis(trifluoromethanesulfonyl)imide

Refernces

• 1、 Wibowo, Rahmat,Aldous, Leigh,Jones, Sarah E. Ward,Compton, Richard G.. "The electrode potentials of the Group i alkali metals in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide". . p. 276 - 280. Retrieved 2010.
• 2、 -. "Preparation method of lithium bis (trifluoromethanesulfonyl) imide". Paragraph 0038-0046. . Retrieved 2021/01/11.
• 3、 -. "New process of bis-trifluoro sulfonimide salt". Paragraph 0062; 0063; 0066; 0067. . Retrieved 2019/06/12.