Fluorene-d10

Base Information

• Chemical Name: Fluorene-d10
• CAS No.: 81103-79-9
• Molecular Formula: C13H10
• Molecular Weight: 176.143
• Hs Code.: 28459000
• European Community (EC) Number: 685-823-9
• DSSTox Substance ID: DTXSID2052730
• Nikkaji Number: J674.568G
• Wikidata: Q81976725
• Mol file: 81103-79-9.mol

Synonyms:Fluorene-d10;81103-79-9;1,2,3,4,5,6,7,8,9,9-decadeuteriofluorene;9H-Fluorene-1,2,3,4,5,6,7,8,9,9-d10;Perdeuterofluorene;Fluorene D10;DTXSID2052730;Fluorene-d10, analytical standard;HY-W026772S;C13D10;C13-D10;CS-T-23774;MS-22946;Fluorene D10 10 microg/mL in Cyclohexane;CS-0254931;Fluorene-d10, 98 atom % D, 99% (CP);D98115

Chemical Property of Fluorene-d10

Chemical Property:

• Vapor Pressure: 0.003mmHg at 25°C
• Melting Point: 115-118 °C(lit.)
• Refractive Index: 1.645
• Boiling Point: 293.6 °C at 760 mmHg
• Flash Point: 133.1 °C
• PSA: 0.00000
• Density: 1.188 g/cm³
• LogP: 3.25780
• Storage Temp.: room temp
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 176.141017778
• Heavy Atom Count: 13
• Complexity: 165

Purity/Quality:

99% ^*data from raw suppliers

Fluorene-D10 ^*data from reagent suppliers

Safty Information:

• Pictogram(s): N
• Hazard Codes: N
• Statements: 50/53
• Safety Statements: 22-24/25-61

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Polycyclic Aromatic Hydrocarbons
• Canonical SMILES: C1C2=CC=CC=C2C3=CC=CC=C31
• Isomeric SMILES: [2H]C1=C(C(=C2C(=C1[2H])C3=C(C(=C(C(=C3C2([2H])[2H])[2H])[2H])[2H])[2H])[2H])[2H]

Technology Process of Fluorene-d10

There total 2 articles about Fluorene-d10 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

9H-fluorene (86-73-7) → 9H-fluorene-d10 (81103-79-9)

Guidance literature:

With water-d2; isopropyl alcohol; In n-heptane; at 120 ℃; Flow reactor;

DOI:10.1246/BCSJ.20200325

Reference yield:

acetylene-d2 (1070-74-2) → 9H-fluorene-d10 (81103-79-9)

Guidance literature:

With fired clay fragments; pyrographite; at 650 ℃;

DOI:10.1039/jr9390000429

Reference yield: 88.0%

9H-fluorene-d10 (81103-79-9) + benzaldehyde (100-52-7) → 9-benzylidene-9H-fluorene-1,2,3,4,5,6,7,8-d8

Guidance literature:

Alkaline conditions; Inert atmosphere; Schlenk technique;

DOI:10.1021/jacs.1c09406

upstream raw materials:

acetylene-d2

9H-fluorene

Downstream raw materials:

fluoren-9-one-d₈

Refernces

• 1、 Boix, Carmen,Poliakoff, Martyn. "Efficient H-D exchange of aromatic compounds in near-critical D2O catalysed by a polymer-supported sulphonic acid". . p. 4433 - 4436. Retrieved 2007/10/03.